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Digitale Medien

Inclusions between large flat organic molecules; the induction of columns and mesophases (1996)

Praefcke, Klaus ; Holbrey, John D.

Springer

Journal of inclusion phenomena and macrocyclic chemistry 24 (1996), S. 19-41

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Details

ISSN: 1573-1111

Schlagwort(e): Arenes ; electron donor-acceptor complexes ; heterocycles ; induction phenomena ; liquid ; crystals ; metallomesogens ; radial multiynes

Quelle: Springer Online Journal Archives 1860-2000

Thema: Chemie und Pharmazie

Notizen: Abstract We describe here an overview on the formation of mesophases by the interaction between large flat aromatic cored molecules and relatively small organic electron acceptors which form stacked, sandwich-like columnar π-π electron donor-acceptor complexes. The inclusion of suitable donor and acceptor components may be used to induce columnar mesophases in mixtures of compounds which can be either mesomorphic or non-mesomorphic in the pure state. With judicious choice of donor and acceptor partners, induced mesophases of remarkable range and thermal stability can be prepared.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1007/BF01053424

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