ISSN:
1572-8862
Keywords:
NMR
;
tin(II)chloride
;
insertion
;
platinum
;
platinum–tin bond
Source:
Springer Online Journal Archives 1860-2000
Topics:
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
Abstract The first 119Sn NMR evidence for the presence of direct platinum–tin bond in solution has been obtained for PtCl(SnCl3)(bdpp) complex (bdpp = (2S,4S)-2,4-bis(diphenylphosphino)pentane). Various PtCl2(L2) complexes (L2 = heterobidentate P−P, P−O, P−N, P−S chelating ligands) have been reacted with tin(II)chloride resulting in the formation of the corresponding PtCl(SnCl3)(L2) derivatives. Tin(II)chloride has been inserted into the Pt−Cl bond transto the harder donor atom of the L2 ligand.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1023/A:1022683111775
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