ISSN:
0009-2940
Keywords:
Phosphorus heterocycles
;
Binaphthophosphole
;
Atropisomerism
;
Binaphthophosphepine
;
Hydroformylations
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Binaphthophospholes and binaphthophosphepines have recently been synthesized. These are the first representatives of a new class of chiral ligands that include within the same structure an endocyclic phosphorus donor, a local C2 symmetry and an axially chiral core. In this review we discuss the synthesis, chemical behaviour and first applications in asymmetric catalysis of these novel derivatives.
Additional Material:
4 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19971300503