ISSN:
0538-8066
Schlagwort(e):
Chemistry
;
Physical Chemistry
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Chemie und Pharmazie
Notizen:
The reactions of ground-state S(3PJ) atoms with thiirane, methylthiirane, and trans-2,3-dimethylthiirane have been studied by flash photolysis-VUV kinetic absorption spectroscopy. From the analysis of the S(3PJ) decay plots the following rate constants were determined: (1.4 ± 0.2) × 1013, (2.7 ± 0.3) × 1013 and (4.0 ± 0.2) × 1013 (in cm3 mol-1 s-1 units) for thiirane, methylthiirane and trans-2,3-dimethylthiirane, respectively, showing an upward trend with increasing methylation.
Zusätzliches Material:
5 Ill.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1002/kin.550160710
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