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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Colloid & polymer science 261 (1983), S. 825-833 
    ISSN: 1435-1536
    Keywords: Polymers ; Slow-brittle-fracture ; Toughness ; Caustics
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract A slow crack growth was achieved in initially edge-cracked specimens made of a high-molecular weight PMMA by regulating the cross-head speed of loading by a computer-driven testing machine. The strain rate $$\dot \varepsilon $$ used during the tests varied between $$\dot \varepsilon $$ =1× l0−6 s−1 and 1×10−4 s−1. It was shown that, in this zone of slow quasi-static loading of brittle polymethylmethacrylate specimens under conditions of plane stress, the crack initiated for a critical value of loading, at some characteristic zone of strain-rate variation at the crack tip. It was established that for strain rate between $$\dot \varepsilon $$ =0.18×10−5 s−1 and $$\dot \varepsilon $$ =0.45×10−4 s−1 brittle cracks were propagating always slowly with velocities in the range ofc=3 to 5×10−2 m/s. For values ofv s outside this transition zone fracture was typically brittle with high crack-propagation velocities. As the strain rate was varying beyond the stable low-velocity region, a two-step crack velocity pattern was operative, where the one step took always low values, and the other step corresponded to crack-propagation velocities significantly higher than these limits, tending to typical brittle-fracture velocities of the material. Oscillations of the velocityc at the transition zones, or, in many cases all over the zone of slow propagation of the crack, indicated the unstable character of crack propagation, influenced by different stress raisers and especially by the opposite longitudinal boundary of the specimen. Stress intensity factor values during crack propagation, evaluated from the front (cuspoid) and the rear (external) caustic, which remained alwaysk g-dominant, were following similar trends as the variation of the crack propagation velocity.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 28 (1988), S. 610-625 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The influence of the hard or soft inclusions and the mesophase layers in either a soft-hard-soft or hard-soft-hard combination of biphase plates submitted to dynamic tensile loads on the fracture mode and bifurcation process in both phases was investigated in this paper. It was assumed that the soft or hard matrix is infolding the hard or soft inclusion of the plate, so that the plate constitutes a meridional section of the representative volume element of a unidirectional fiber composite, or a principal section of a particulate. The influence of the mechanical properties of either phase on the crack propagation velocity and the initiation of crack bifurcation was studied by using high-speed photography and dynamic caustics. The results showed that the propagating crack tended to bifurcate either in the brittle or in the mesophase layer under certain conditions of propagation velocity. It was shown that bifurcation of a propagating crack depends on the elastic moduli and Poisson's ratios of the phases, as well as on the extent of the mesophase layer, which depended on the adhesion quality of phases.
    Additional Material: 17 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Brookfield, Conn. : Wiley-Blackwell
    Polymer Composites 9 (1988), S. 229-236 
    ISSN: 0272-8397
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: High-impact polystyrene (HIPS) constitutes a mechanically attractive composite, consisting of a glassy matrix and a rubberlike particle phase (gel phase). Dynamic mechanical spectroscopy was performed for the polystyrene matrix for three different types of HIPS as well as for the concentrated gel-phase material, at the vicinity of the respective glass-transition temperatures (Tg). An approximate estimation of the gel-phase modulus was attempted by using known mechanical models. A comparison with experiments was also made. The modulus of the composite was found to be lower than the theoretical lower bound for particulate composites. This was attributed to a separate phase between gel particles and the matrix. A diffusion-type variation of the modulus of this mesophase layer was estimated, and a correlation between calculated fitting parametric exponents and impact behavior of HIPS was found. Moreover, the Tgs of the materials under investigation were also measured with two independent methods. It was found that all types of HIPS presented higher Tgs than the pure matrix by 5 to 10°C with the highest Tg found being that of the gel-enriched material. The shift of Tgs to higher temperatures was attributed to an eventual increase of the effective cross-link density of the matrix because of grafting.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Brookfield, Conn. : Wiley-Blackwell
    Polymer Composites 7 (1986), S. 1-8 
    ISSN: 0272-8397
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The dynamic mechanical properties of composite materials, consisting of an epoxy matrix filled with iron particles, were determined over a temperature range. The storage- and loss moduli were evaluated in a Dynastat apparatus, with the parameters being the volume fraction of filler and the test frequency. A theoretical model was developed for comparing the experimental results with the theoretical predictions. A satisfactory correlation was obtained for the glassy region of the composite.
    Additional Material: 13 Ill.
    Type of Medium: Electronic Resource
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