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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Colloid & polymer science 262 (1984), S. 929-938 
    ISSN: 1435-1536
    Keywords: Fibrous composites ; mesophase ; unfolding models
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract A theoretical model was introduced for the evaluation of the boundary layer developed between the main phases during the preparation of unidirectional fiber composites. It has been shown that this thin layer influences considerably the physical properties of the composite. It was assumed that the physical properties of themesophase unfold from those of the hard-core fibers to those of the softer matrix. Thus, a multicylinder model was assumed improving the classical two-cylinder model introduced by Hashin and Rosen for the representative volume element of the composite. Based on thermodynamic phenomena appearing at the glass transition temperatures of the composite and concerning the positions and the sizes of the heat-capacity jumps there, as well as on the experimental values of the longitudinal elastic modulus of the composite, the extent of the mesophase and the mechanical properties of the composite may be accurately evaluated. This version of the model is based on a previous one concerning a multilayer model, but it is considerably improved in order to take into consideration, in a realistic manner, the physical phenomena developed in fiber reinforced composites.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Colloid & polymer science 264 (1986), S. 561-569 
    ISSN: 1435-1536
    Keywords: Fibrous composites ; mesophase ; longitudinal elastic modulus ; transverse elastic modulus ; major Poisson ratio
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Expressions for the evaluation of the transverse and longitudinal elastic moduli and the major Poisson ratio of unidirectional fiber composites are derived. The model described is based on the correct version of Kerner's model, which in our case is conveniently modified by introducing a mesophase layer between the fiber and the matrix in the representative volume element surrounding the typical fiber. The expression for the longitudinal elastic modulus derived in this paper, and the law of mixtures already presented in previous papers, give concordant results. Therefore, the law of mixtures, taking the mesophase also into account, and the two-term unfolding model for the mesophase are used for the evaluation of its extent and its properties. The model was applied to a glass filament-epoxy resin composite and its predictions were found to be in good agreement with the experimental data.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Colloid & polymer science 261 (1983), S. 825-833 
    ISSN: 1435-1536
    Keywords: Polymers ; Slow-brittle-fracture ; Toughness ; Caustics
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract A slow crack growth was achieved in initially edge-cracked specimens made of a high-molecular weight PMMA by regulating the cross-head speed of loading by a computer-driven testing machine. The strain rate $$\dot \varepsilon $$ used during the tests varied between $$\dot \varepsilon $$ =1× l0−6 s−1 and 1×10−4 s−1. It was shown that, in this zone of slow quasi-static loading of brittle polymethylmethacrylate specimens under conditions of plane stress, the crack initiated for a critical value of loading, at some characteristic zone of strain-rate variation at the crack tip. It was established that for strain rate between $$\dot \varepsilon $$ =0.18×10−5 s−1 and $$\dot \varepsilon $$ =0.45×10−4 s−1 brittle cracks were propagating always slowly with velocities in the range ofc=3 to 5×10−2 m/s. For values ofv s outside this transition zone fracture was typically brittle with high crack-propagation velocities. As the strain rate was varying beyond the stable low-velocity region, a two-step crack velocity pattern was operative, where the one step took always low values, and the other step corresponded to crack-propagation velocities significantly higher than these limits, tending to typical brittle-fracture velocities of the material. Oscillations of the velocityc at the transition zones, or, in many cases all over the zone of slow propagation of the crack, indicated the unstable character of crack propagation, influenced by different stress raisers and especially by the opposite longitudinal boundary of the specimen. Stress intensity factor values during crack propagation, evaluated from the front (cuspoid) and the rear (external) caustic, which remained alwaysk g-dominant, were following similar trends as the variation of the crack propagation velocity.
    Type of Medium: Electronic Resource
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