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  • Chemistry  (30)
  • rust resistance  (5)
  • Earth atmosphere  (2)
  • 11
    Electronic Resource
    Electronic Resource
    Miscibility and interaction studies on some aqueous polymer blend solutions by ultrasonic and rheological techniques (1994)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 51 (1994), S. 1559-1565 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The aqueous solutions of poly(ethylene oxide)-polyacrylic acid, poly(vinyl pyrrolidone)-poly(vinyl alcohol), and poly(ethylene oxide)-poly(vinyl alcohol) blends have been studied by ultrasonic, rheological, and viscometric techniques. Extensive investigation over a wide range of concentrations, temperatures, compositions, pH, and shear rates indicate the degree of miscibility, extent of interaction between the polymers, and stoichiometry of the polymer complexes formed by the strong interaction between the polymers in solutions. These investigations indicate the miscibility of poly(ethylene oxide)-polyacrylic acid and poly(ethylene oxide)-poly(vinyl pyrrolidone) blends and the immiscibility of poly(ethylene oxide)-poly(vinyl alcohol) blends in conformity with other reported investigations. © 1994 John Wiley & Sons, Inc.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1994.070510905
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  • 12
    Electronic Resource
    Electronic Resource
    Studies on impact modification of polystyrene (PS) by ethylene-propylene-diene (EPDM) rubber and its graft copolymers. I. PS/EPDM and PS/EPDM-g-styrene blends (1990)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 40 (1990), S. 685-692 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Ethylene-propylene-diene (EPDM) rubber is an excellent rubber for outdoor use. High impact polystyrene (PS) containing EPDM rubber may show improved weathering resistance. PS is incompatible with EPDM; hence bulk polymerization technique is adopted for the synthesis of graft products which show limited compatibility with PS. Two initiators were chosen at two different working temperatures to produce high grafting efficiency and grafting percentage. In the present system, it is shown that the graft copolymer and polystyrene compositions show higher improved impact strength behavior than that of the products based upon simple dispersion of EPDM in polystyrene.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1990.070400505
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  • 13
    Electronic Resource
    Electronic Resource
    Studies on impact modification of polystyrene (PS) by ethylene-propylene-diene (EPDM) rubber and its graft copolymers. III. PS/EPDM-g-(styrene-co-maleic anhydride) blends and its relative performance (1990)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 40 (1990), S. 701-707 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The graft copolymer of ethylene-propylene-diene (5-ethylidene-2-norbornene) rubber with styrene and maleic anhydride is synthesized, characterized, and blended with polystyrene. The tensile and the impact behaviors of the blends were investigated. The relative performance of EPDM-g-(styrene-co-maleic anhydride) as impact modifier for polystyrene has been evaluated.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1990.070400507
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  • 14
    Electronic Resource
    Electronic Resource
    Drag-reduction efficiency, shear stability, and biodegradation resistance of carboxymethyl cellulose-based and starch-based graft copolymers (1991)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 43 (1991), S. 1091-1101 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Graft copolymers of carboxymethyl cellulose and starch with polyacrylamide have been synthesized by grafting acrylamide onto carboxymethyl cellulose and starch, respectively, using a ceric-ion-initiated solution polymerization technique. These graft copolymers have been tested for their drag-reduction effectiveness, shear stability, and biodegradability. It has been shown that grafting enhances the drag-reduction effectiveness and shear stability and also that these factors are very much dependent on the length and number of grafts in the molecule. None of the graft copolymer solutions shows any microbial degradation up to 10 days.
    Additional Material: 15 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1991.070430609
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  • 15
    Electronic Resource
    Electronic Resource
    Compatibility and thermal stability studies on PVC/chlororubber-20-graft polyblend-styrene-vinyl acetate-acrylonitrile blends. IICorrected proofs Received February 27, 1984 (1984)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 29 (1984), S. 1653-1660 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Compatibility and Thermal stability studies have been performed on PVC blends with chlororubber-20-graft polyblend-styrene-vinyl acetate-acrylonitrile (1:1:1) [CR-20gp-SVAAN (1:1:1)]. The grafting of styrene, vinyl acetate, and acrylonitrile onto chlororubber-20 backbone chain generates some amount of heterogeneity in the system. The compatibility behavior of PVC/CR-20gp-SVAAN (1:1:1) blends has been reflected in the ultrasonic velocity and absolute viscosity vs. composition plots of the blend. These blends have been found to be thermally miore stable than PVC/chlororubber-20 blends, but less stable than PVC/KM-365B blends. The rate of degradation is equal to that of the PVC/chlororubber-20 blends. The results have been discussed on the basis of compatibility, stabilizing, and destabilizing behavior of various component polymers with PVC matrix.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1984.070290519
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  • 16
    Electronic Resource
    Electronic Resource
    Studies on impact modification of polystyrene (PS) by ethylene-propylene-diene (EPDM) rubber and its graft copolymers. II. PS/EPDM-g-(styrene-co-methylmethacrylate) blends (1990)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 40 (1990), S. 693-699 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The toughness of a polymer blend is one of the major factors deciding its practical application. An impact modified polystyrene (PS) is usually a multiphase system consisting of the thermoplastics and an elastomeric component. The heterogeneous character of such a system and the interfacial adhesion between the components determine its impact strength. The graft copolymer of ethlene-propylene-diene (5-ethylidene-2-norbornene) rubber with styrene and methylmethacrylate is synthesized, characterized, and blended with polystyrene to improve its impact strength. It is observed that there is improvement in impact strength with the subsequent decrease of tensile strength. The improved impact strength has been discussed in terms of morphology, compatibility, and interfacial adhesion of graft copolymers with PS matrix.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1990.070400506
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  • 17
    Electronic Resource
    Electronic Resource
    Use of natural rubber prophylactics waste as a potential filler in styrene-butadiene rubber compounds (1996)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 61 (1996), S. 2035-2050 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Owing to the unstable nature of the latex compound and the strict specifications in the quality of latex products such as condoms and examination gloves, the rejection in the latex industry comes to about 10 to 15% of the rubber consumed. These latex rejects contain about 95% rubber hydrocarbon of very high quality. A cost-effective technique has been developed for the reuse of natural rubber (NR) prophylacties waste in styrene-butadiene rubber (SBR). The influence of powdered latex rejects on the curing characteristics, mechanical properties, and failure behavior of SBR has been investigated. More emphasis is placed on the effect of both particle size and the loading of latex waste filler. Swelling studies were carried out to establish the degree of crosslinking of SBR and to assess the extent of interaction between the matrix and latex waste filler of varying particle sizes. A three layer model has been set up to study the diffusion of sulfur from the matrix phase to the filler phase. Scanning electron microscopy has been used to analyze the particle morphology, filler dispersion, and filler-matrix interface adhesion. The results of the study revealed that NR prophylactics rejects can be used effectively as a potential filler in SBR up to about 40 phr loading. © 1996 John Wiley & Sons, Inc.
    Additional Material: 23 Ill.
    Type of Medium: Electronic Resource
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  • 18
    Electronic Resource
    Electronic Resource
    Drag reduction by polymer-polymer mixtures (1988)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 36 (1988), S. 837-858 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: An extensive study on the turbulent drag reduction caused by the various mixtures of polyacrylamide, purified guargum, xanthangum, and their graft copolymers has been conducted at low concentrations and Re = 14,000 using a turbulent flow rheometer. It has been found in most of the cases that the drag reduction caused by mixtures shows a positive deviation from the linearly additive straight line. This effect is more prominent when the drag reduction caused by both the constituents differ appreciably. In most of the cases, the drag reduction caused by the mixtures is higher than the DR caused by either of the constituent polymers; however, the drag reduction caused by the mixture is less than the sum of the drag reduction caused by both the constituents at their respective concentration in the mixture. It has also been noticed that there is no evidence of synergism in these mixtures at low concentrations.
    Additional Material: 13 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1988.070360409
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  • 19
    Electronic Resource
    Electronic Resource
    Turbulent drag effectiveness and shear stability of xanthan-gum-based graft copolymers (1989)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 37 (1989), S. 2933-2948 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A number of graft copolymers of xanthan gum and polyacrylamide have been synthesized by grafting acrylamide onto xanthan gum using the ceric-ion-initiated solution polymerization technique. The effects of various synthesis parameters such as amount of catalyst, reaction time, and ratio of xanthan and acrylamide on drag reduction effectiveness of the graft copolymers have been studied. The scaling up of grafting reaction has been accomplished in 40-L reactor. The drag reduction effectiveness of the graft copolymers is investigated over a wide range of concentrations and Reynolds numbers. It is shown that the maximum drag reduction obtainable in xanthan gum solutions above 300 ppm can be obtained in solutions of graft copolymers at concentrations of 100-150 ppm. The grafting also improves the shear stability at higher Reynolds numbers. The shear stability of the graft copolymers at constant wall stress has been found to be superior to polyacrylamide and the mixtures of polyacrylamide and xanthan gum. In general, the shear stability of graft copolymers and polyacrylamide is shown to increase with concentration. The drag reduction characteristics and shear stability have been discussed in terms of structural features of the graft copolymers. The drag reduction characteristics of the graft copolymers are found to be similar to those of flexible polymers.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1989.070371012
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  • 20
    Electronic Resource
    Electronic Resource
    Investigation on multiphase polymeric systems of poly(vinyl chloride). I. PVC-chlororubber-20-gp-styrene-acrylonitrile (2 : 1) blends (1989)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 37 (1989), S. 2491-2515 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A graft copolymer [chlororubber-20-gp-styrene-acrylonitrile (2 : 1)] has been synthesized by a solution precipitation polymerization technique grafting styrene and acrylonitrile onto chlororubber-20 main chain. The graft copolymer has been characterised by elemental analysis, IR spectroscopy, and viscometry. It has been blended with PVC by melt mixing using a Brabender plasticorder and extrusiograph. The mechanical properties such as flexural and tensile strengths and impact strength of the blends have been studied to evaluate its performance as an impact modifier. The behavior of PVC-chlororubber-20-gp-styrene-acrylonitrile (2 : 1) blends has also been compared with PVC-chlororubber-20 and PVC-KM-365B (a commercial acrylate modifier) blends. The thermal behavior of these blends has also been studied. It has been found that PVC-chlororubber-20-gp-styrene-acrylonitrile (2 : 1) blends have higher impact strength than PVC-chlororubber-20-gp blends though the PVC-KM-365B blends have the highest impact strength. Based on the authors' previous compatibility studies along with present X-ray diffraction studies and the morphological investigation of the fractured surface by scanning electron microscopy, the mechanical behavior of these blends have been explained in the framework of existing theories. A model has been proposed to account for the optimum dispersion and adhesion of graft polyblends of chlororubber-20 in PVC matrix.
    Additional Material: 15 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1989.070370904
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