ISSN:
0044-2313
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
On the chemistry of transition metal alkyl compounds. IX. Experiments on the preparation of organyl derivates of vanadium oxidetrichloride. Preparation and properties of phenyl vanadium oxidedichlorideReactions of vanadium oxidetrichloride with alkyl and aryl compounds of zinc, mercury and tin are reported. At low temperatures phenyl vanadium oxidedichloride could be isolated in form of red crystals and characterized by its UV and IR spectrum, and formation of a bipyridyl complex.
Notes:
Es wird über Reaktionen des Vanadinoxidtrichlorids mit Organylverbindungen des Zinks, Quecksilbers und Zinns berichtet. Dabei konnte das Phenylvanadinoxiddichlorid bei tiefer Temperatur in kristalliner Form isoliert und durch das UV- und IR-Spektrum sowie durch die Bildung eines Dipyridylkomplexes charakterisiert werden.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19723900307
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