ISSN:
0044-2313
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Complex Catalysis. X. α-Olefin Insertion into the Trihapto-allyl-nickel(II) Group: Synthesis and Properties of Bis(pentahapto-1,8-nonadiene-5-yl-nickel(II)-difluorophosphate)By reaction of (h3-C3H5)2Ni with difluorophosphoric acid in ether under addition of 1,5-hexadiene bis(pentahapto-1,8-nonadiene-5-yl-nickel(II)-difluorophosphate) could be synthesized in good yield, proving thereby preparatively the 1,2-addition of the trihapto-allyl-nickel(II) fragment to the double bond of an α-olefin for the first time.
Notes:
Durch Reaktion von (h3-C3H5)2Ni mit Difluorophosphorsäure in Ether unter Zusatz von 1,5-Hexadien konnte in guter Ausbeute Bis(pentahapto-1,8-nonadien-5-yl-nickel(II)-difluorophosphat) dargestellt und damit erstmalig die 1,2-Addition des Trihaptoallyl-nickel(II)-Fragments an die Doppelbindung eines α-Olefins präparativ bewiesen werden.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19794580137
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