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  • Chemistry  (2)
  • Polymer and Materials Science  (1)
  • 1
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 26 (1986), S. 1208-1212 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: This paper reports studies on polystyrene/poly-(vinylmethylether) blends to elucidate phase decomposition phenomena. Small angle neutron scattering (SANS) and temperature jump light scattering (TJLS) techniques were used to study both static and kinetic properties. The SANS methods were used to characterize the blends with respect to phase diagram, the Flory-Huggins interaction parameter, and the critical fluctuation length as a function of temperature. From the TJLS experiments, we have demonstrated the possibility of two kinds of phase decomposition mechanisms which should lead to distinct morphology and material properties.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 36 (1998), S. 2745-2750 
    ISSN: 0887-6266
    Keywords: polymer blends ; hydrogen bonding ; small-angle neutron scattering ; Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Deuterium-labeled polystyrene modified by random distributions of the comonomer p-(1,1,1,3,3,3-hexaflouro-2-hydroxyisopropyl)-α-methyl-styrene [DPS(OH)] has been blended with poly(butyl methacrylate) (PBMA) and studied with small-angle neutron scattering (SANS). Miscibility is induced via hydrogen bonding between the DPS(OH) hydroxyl group and PBMA carbonyl groups. The data suggest that the nature of the miscible-phase structure in these blends differs from that of the usual homopolymer blends at small scattering angles, which we attribute to the short-range site specific nature of the hydrogen bond interaction. © 1998 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 36: 2745-2750, 1998
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 26 (1986), S. 3-8 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A systematic study of static and kinetic phase behavior of deuterated polystyrene/poly(vinylmethylether) blends is presented in this paper. The static properties are studied by the small angle neutron scattering techniques and the kinetics of phase decomposition are studied by the temperature jump light scattering; technique. This procedure provides detailed information about phase behavior with regard to both thermodynamics and kinetics.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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