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  • 1
    Electronic Resource
    Electronic Resource
    Competing growth kinetics in simultaneously crystallizing and phase-separating polymer blends (2002)
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 116 (2002), S. 7311-7315 
    Details
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The kinetic interplay between crystal superstructure growth and late-stage liquid phase coarsening in a polymer blend has been examined. By controlling the relative quench depths for liquid–liquid phase separation and crystallization, the growth kinetics of the characteristic length scales of the simultaneous ordering processes show a crossover from crystallization dominated to phase-separation dominated behavior. Based on a scaling argument for late-stage coarsening during spinodal decomposition, we argue that this kinetic crossover is inevitable in a blend for which the critical temperature of liquid–liquid phase separation is well above the equilibrium melting temperature of the blend. © 2002 American Institute of Physics.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1063/1.1464537
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    Paper (German National Licenses)
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  • 2
    Electronic Resource
    Electronic Resource
    Equilibrium structure of hydrogen-bonded polymer blends (1998)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 36 (1998), S. 2745-2750 
    Details
    ISSN: 0887-6266
    Keywords: polymer blends ; hydrogen bonding ; small-angle neutron scattering ; Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Deuterium-labeled polystyrene modified by random distributions of the comonomer p-(1,1,1,3,3,3-hexaflouro-2-hydroxyisopropyl)-α-methyl-styrene [DPS(OH)] has been blended with poly(butyl methacrylate) (PBMA) and studied with small-angle neutron scattering (SANS). Miscibility is induced via hydrogen bonding between the DPS(OH) hydroxyl group and PBMA carbonyl groups. The data suggest that the nature of the miscible-phase structure in these blends differs from that of the usual homopolymer blends at small scattering angles, which we attribute to the short-range site specific nature of the hydrogen bond interaction. © 1998 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 36: 2745-2750, 1998
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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    Paper (German National Licenses)
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