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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Colloid & polymer science 261 (1983), S. 409-411 
    ISSN: 1435-1536
    Keywords: n-alkane ; single crystal ; elastic tensor ; phase transition
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract For the first time directly measured elastic tensor components of C36H74 single crystals are presented as a function of temperature. The data are compared to theoretical results obtained for polyethylene.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1435-1536
    Keywords: High performance Brillouin spectroscopy ; elastic tensor ; birefringence ; scattering geometries ; D-function
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract General aspects of high performance Brillouin spectroscopy in polymers using special scattering geometries such as 90A-scattenng geometry are discussed. Technical improvements are reported resulting in absolute accuracies up to 0.05 % for sound velocity determination. A method of data analysis is presented delivering simultaneously the complete set of elastic stiffness constants. The influence of birefringence on the Brillouin line shifts in anisotropic polymeric systems is estimated and techniques to reduce this influence are proposed. The determination of the principal refractive indices by Brillouin spectroscopy is discussed. Furthermore, a quantityD X , which is sensitive to hypersonic relaxation processes, is introduced.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Some physical investigations of segmented block copolymers of uniform chain length and defined structure and their constituents are described. Special attention was payed to the thermal behaviour of these new substances with respect 1. to the phase transformations in the solid and liquid state and 2. to the thermal stability of the materials. Several of these oligomers show phase transitions in the solid state. In some instances, the morphology of the solid material depends strongly on the sample history. The influence of the crystallization conditions is discussed. For the special case of esters of 4,4′-isopropylidenediphenol (bisphenol A) with isophthalic acid detailed investigations by dielectric and Brillouin spectroscopy of the glass-forming process are presented.
    Additional Material: 22 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Journal of Raman Spectroscopy 17 (1986), S. 113-116 
    ISSN: 0377-0486
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The temperature dependence of internal NO2 modes has been investigated by polarized Raman scattering from potassium barium nitrite single crystals. The frequencies of the symmetric stretching and bending modes are determined for the three non-equivalent NO2 sites present at room temperature. The structural implications associated with the phase transition at about 200 K are derived from line splittings and relative intensities. The experimental results are consistent with an order-disorder transition and no soft lattice mode has been found.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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