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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 43 (1994), S. 455-460 
    ISSN: 0006-3592
    Keywords: E. coli ; inclusion body ; disc stack centrifuge ; Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A simple and rapid spectrophotometric method for measuring recombinant inclusion body concentrations in the presence of Escherichia coli cell debris has been applied to monitoring the performance of an industrial disc stack centrifuge. Turbidimetric measurements were made at two wavelengths, i.e., 600 nm and 420 nm, and the ratios of OD600nm/OD420nm related to the particle composition in suspension. The principle behind the technique is that inclusion body particles scatter light at 600 nm more effectively than do smaller cell debris particles when compared with the degree of light scatter at 420 nm. This technique may have broad potential application in developing an automatic monitoring and control system for industrial-scale inclusion body recovery. © 1994 John Wiley & Sons, Inc.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1040-0397
    Keywords: Ultrasound ; Mercury ; Deposition ; Anodic stripping voltammetry ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The fast electrochemical deposition of both mercury and amalgam films, a crucial step in analytical anodic stripping voltammetry, is demonstrated to occur in the presence of power ultrasound emitted from an immersion horn probe which was placed opposite the working electrode in a conventional three electrode cell. Due to considerably enhanced mass transport the rate of deposition is strongly increased compared to ‘silent’ conditions. The total amount of mercury adhering to a glassy carbon electrode surface, however, is limited to a ‘thin film’ of microscopically small droplets of mercury as shown by atomic force microscopy and voltammetry. Due to surface forces induced by ultrasound, abrasion of some of the deposit occurs and after a certain period of time the parallel electro-deposition and abrasion processes reach a ‘steady state’.The deposition of mercury in the presence of Pb2+ or Cu2+ results in the formation of an amalgam and well-defined, very sharp ‘stripping’ responses for the oxidation process of the corresponding amalgam were detected. The merit of insonation in analytical electrode preconcentration techniques is dicussed.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 24 (1986), S. 27-38 
    ISSN: 0887-6266
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The rheological properties of fractionated thermotropic nematic polyesters 4,4′-dioxy-2,2′-dimethyl azoxybenzenenonanediyl (n = 7) (AZA-9) and dodecanediyl (n = 10) (DDA-9) have been determined under oscillatory shear in the nematic and isotropic phase. A markedly more pronounced shear thinning characterizes the polydisperse DDA-9 polymer as compared to the fractionated polymer in the nematic state. This difference becomes less pronounced in the isotropic phase. In all cases, the elastic compliance J′ in the isotropic state is much lower than in the nematic state. The values of relaxation time λ, although lower in the isotropic state, are not very different in the nematic state. The loss tangent tan δ is significantly higher in the isotropic phase for lower molecular weights. For molecular weights of 13,000 and above, this difference becomes smaller and shifts to lower angular frequencies. For AZA-9 and DDA-9, ηω*→0 the limit of the dynamic viscosity can be represented by η* = Mna with a value of α similar for both phases and approximately equal to 4.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 24 (1986), S. 827-837 
    ISSN: 0887-6266
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Infrared spectroscopy has been used to analyze the microstructures of liquid-crystalline polymers in various mesophases. It was quite evident that there is little indication of conformational order associated with the flexible polymethylene sequences in the nematic or isotropic phases. However, additional spectroscopic evidence does suggest that polyesters with an even number of methylene units have a higher degree of lateral order when compared to those with an odd number in the liquid-crystalline state.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
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  • 5
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Thermal and biological properties of tin-modified cellulose derived from cotton are described. The inception temperature of degradation for tin-modified cellulosic products is inferior to that of cotton itself, but the heats of degradation in air are less than that of cotton consistent with the modified products being superior in this respect. Degradation of the modified materials in helium as monitored by coupled thermogravimetric analysis-mass spectroscopy shows that degradation occurs through a series of complex steps with the evolution of products characteristic of both the tin-containing and cellulose materials. The tin-modified cellulose was tested against five fungi using disk and protein assays. The fungi tested are typical and widespread, and these tests provide a good indication of the applicability of such products as retarders of fungi-related rot and mildew. Most of the tested samples showed good inhibition of the tested fungi.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Surface and Interface Analysis 14 (1989), S. 7-12 
    ISSN: 0142-2421
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: The Interfacial reactions between Al and RuO2, MoOx and WNx diffusion barriers on Si (100) wafers have been studied. The diffusion barrier structures were analyzed before and after various heat treatments using Auger electron spectroscopy (AES) and cross-sectional transmission electron microscopy (XTEM). Al was found to reduce the oxides of both Ru and Mo. A 100 Å thick Al2O3 layer developed between the Al and the RuO2 films during annealing at 500°C for 30 minutes. The formation of interfacial Al2O3 efficiently prevents Al penetration but may cause a too high contact resistance for applications in contact structures of microelectronic devices. The WNx barrier was stable after annealing at 600°C for 30 minutes, if the film was exposed to air prior to Al deposition. If, instead, the Al was deposited in situ, the structure failed after annealing at 500°C due to a reaction between Al and W giving WAl12. A thin Al2O3 layer was detected between the Al and the WNx films of the air exposed sample. This layer had the effect of retarding the Al-W reaction and thereby raised the failure temperature of the barrier by at least 100°C.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 5 (1971), S. 885-889 
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The mass spectral cracking patterns of several aromatic perchlorocarbons and perchlorocarbon radicals are reported. These include the first examples of mass spectra of stable carbon free-radical substrates, and they do not differ significantly from those of structurally similar neutral substrates. All the compounds show successive loss of chlorine atoms with very little fragmentation of the carbon skeleton. This class of compounds has potential value to mass spectroscopists as reference standards in the range m/e 300 to 700.
    Additional Material: 2 Tab.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Plant/Operations Progress 3 (1984), S. 18-18 
    ISSN: 0278-4513
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Letters Edition 22 (1984), S. 13-19 
    ISSN: 0360-6384
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Plant/Operations Progress 3 (1984), S. 125-126 
    ISSN: 0278-4513
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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