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  • 1
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Stereospecific Br/O Ac-Substitution at syn- and anti-11-Bromo-2.3-benzotricyclo[4.4.1.0] undecen-4-one. The Retentive Substitution at CyclopropanePossible mechanisms A - G of the nucleophilic substitution at cyclopropane carbons are discussed. Special attention is given to the retentive replacements D and E which hitherto have not been observed. A smooth, stereospecific Br/OAc-substitution under typical SN2-type conditions is described for the syn/anti-isomers 6a and 7a. From the n.m.r. spectra of the four compounds 6a, b and 7a, b it is concluded that these substitutions occur under retention of configuration which is confirmed by X-ray analysis of the crystalline pair 7a, b.
    Notes: Mögliche mechanismen A - G der nucleophilen Substitution an Cyclopropanen werden unter besonderer Berücksichtigung der bisher nicht beobachteten Retention nach D oder E diskutiert. Am Beispiel der syn/anti-Isomeren 6a und 7a wird eine Br/OAc-Substitution beschrieben, die stereospezifisch unter typischen SN2-Bedingungen erfolgt. Aus den NMR-Spektren der vier Verbindungen 6a, b und 7a, b kann man schließen diese Substitutionen unter Retention der Konfiguration ablaufen. Die Röntgenstrukturanalyse des kristallinen Paares 7a, b bestätigt dies.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 93 (1960), S. 1746-1751 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Dehydrodeguelin (IIa) wurde über d,l-Deguelol (IVa) in d,l-Deguelin (Ia) über-geführt. Da IIa schon aus Deguelinsäure (IIIa) dargestellt worden ist, liegt nunmehr die erste Partialsynthese des Deguelins aus IIIa vor. Ferner liefert das durch Natriumborhydrid-Reduktion aus Deguelinol-I (Va) zugängliche Deguelidiol (VIIa bzw. IXa) beim Behandeln mit Mineralsäure unter Pinakolin-Umlagerung d,l-Deguelin. Die Zusammensetzung der im „Rotenonharz“ enthaltenen Rotenoide wurde untersucht, alle in ihm vorkommenden inaktiven Rotenoide konnten in physiologisch aktives Rotenon oder Deguelin umgewandelt werden.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 32 (1992), S. 1545-1549 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The multiple interference effect is one of the major causes of the fluctuation in critical dimension control (CD) and in mark detection for alignment. Suppressing this effect is critical for future photolithography. We propose a new photolithography technique called anti reflective coating on resist (ARCOR), which improves linewidth accuracy and overlay accuracy by suppressing multiple interference. ARCOR consists of relatively simple processes: A clear antireflective film is spun onto the resist prior to the mark detecting for alignment and exposure. The film is subsequently removed and the resist developed in the conventional way. ARCOR differs from ARC, which suppresses the reflection at the resist/substrate interface. ARCOR suppresses the reflection at the air/resist interface. ARCOR allows mark detection and exposure without light intensity-loss and multiple interference. The experiments mainly examine polysiloxane and perfluoroalkylpolyether as ARCOR materials. It is shown that linewidth accuracy can be improved from 0.3 to 0.03 μm. The signal-to-noise ratio of the alignment signal is drastically improved, and the overlay error is about half that of the conventional method. ARCOR is also effective for directly measuring the reflectivity at the resist/substrate interface, which is a key parameter of the multiple interference effect and the halation. Using ARCOR and a thin resist film, the measured ratio of reflected light to incident light indicates the reflectivity at the resist/substrate interface. Because, the probe light does not reflect off the resist surface and the intensity-loss at the resist surface is suppressed. With perfluoroalkylpolyether film, the measurement error is ∼ 1.5%.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 14 (1985), S. 119-130 
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Reverse electron transfer between photogenerated redox pair in bulk aqueous solutions can be efficiently suppressed by collecting the photoliberated electron to the positively charged surface of molecular assemblies such as micelles, bilayers and polymers. Zwitterionic viologen molecules serve as efficient electron carriers, which shuttle between the bulk phase and the surface of molecular assemblies. The molecular assemblies with aligned viologen units at the surface are particularly useful as molecular device for the electron enrichment and storage. Quantitative charge separation of the cage-escaped redox pair can be achieved by the use of the amphiphilic viologen molecular assemblies in combination with the zwitterionic viologen. The lifetime of charge-separated state can be extremely extended in these systems : ca 30 ms for the viologen bilayer and above 1 s for the polymer with pendant viologen. Amphiphilic viologen molecular assemblies also help to increase charge-separation of the photoinduced, intramolecular electron transfer in sensitizeracceptor linked system incorporated into the molecular assemblies. All of these phenomena are ascribed to cooperativity effects of aligned viologen units, which induce electron hopping a long the surface via successive electron exchange between viologen molecules.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 180 (1979), S. 2999-3001 
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 182 (1981), S. 977-988 
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Partial development of the α form crystals in γ nylon 12 has been found to take place by drawing near the melting point. The confirmation of the α form has been made by X-ray diffraction, infrared absorption, and differential scanning calorimetry. The amount of the α form varies depending upon the temperature of drawing and draw ratio, whereas it is almost independent of the rate of drawing. The minimum draw ratio necessary to yield the α form increases as the temperature of drawing decreases. The crystallinity, determined from the density, also increases with the increase in the temperature of drawing and draw ratio, while it decreases slightly with the increase in the rate of drawing. The development of the α form is ascribable to the transformation from the γ form rather than the crystallization from the amorphous region. The total figure of the polymorphism in nylon 12 is proposed.
    Additional Material: 15 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 178 (1977), S. 2413-2419 
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The 13C-chemical shift of β-carbon in the vinyl group of monomers was correlated with the relative reactivity of the monomer in the cationic copolymerizations of substituted styrenes, benzyl vinyl ethers, and phenyl vinyl ethers and also in the copolymerization of substituted styrenes by Ziegler catalysts. It was found that the β-carbon resonates at the higher field, the higher the reactivity of the monomer is. The reverse was the case in the anionic addition reaction of substituted styrene to living polystyrene. The relations were also studied between the 13C-chemical shift and the e-value of the monomer and some direct evidence was obtained for the validity of the Q-e scheme. From these results it was revealed that the 13C-chemical shift of vinyl compounds is an important tool for the examination of the mechanism of polymerization reaction.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 193 (1992), S. 43-51 
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Copolymerization of propene with 1-hexene was performed at 40°C under atmospheric pressure using both aspecific and isospecific catalysts composed of TiCl3/MgCl2 and Al(C2H5)3, and of Solvay type TiCl3 and Cp2 Ti(CH3)2 (Cp: cyclopentadienyl), respectively. The isospecific catalyst gave two kinds of copolymers with different content of 1-hexene, whereas the aspecific catalyst gave a uniform copolymer abundant in 1-hexene. Both copolymers produced with the isospecific catalyst were found to show isotactic stereoregulation in the propylene units. From these results, it was concluded that the catalyst composed of Solvay type TiCl3 and Cp2 Ti(CH3)2 has two kinds of isospecifically active species which differ in the monomer reactivity ratio for propene-1-hexene copolymerization.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 9
    ISSN: 0269-3879
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine
    Notes: A high performance liquid chromatographic (HPLC) system is described for determination of the unsaturated disaccharide (ΔDi-HA) derived from hyaluronic acid (HA) in human urine by digestion with hyaluronidase SD. The effects of eluents on the separation of ΔDi-HA and ΔDi-OS, which is derived from the reaction of chondroitin with the enzyme, have been studied. The established chromatographic conditions were as follows-column: a stainless steel tube (4 mm i.d. × 250 mm) packed with TSKgel NH2-60; eluent: a mixture of acetonitrile and 0.1 M Tris-HCI buffer containing 0.1 M boric acid and 10 mM sodium sulphate, pH 7.0 (64:36, v/v). The strong fluorescence of unsaturated disaccharide after the reaction with 2-cyanoacetamide in alkaline medium was used for post-column detection. The calibration curve for ΔDi-HA was linear in the range 5 pmol-5 nmol with a practical detection limit of 2 pmol. The assay coefficients of variation (n = 5) at 200 pmol for ΔDi-HA and ΔDi-OS were 1.7 and 1.5%, respectively. This HPLC system has been applied to the determination of HA in human urine.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 10
    ISSN: 0269-3879
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine
    Notes: The reactivities between saccharides and primary amino compounds were studied by liquid chromatography on an amino-bonded column and by measurement of the reaction rates of aromatic amines with saccharides. The recoveries from the column and the reaction rates were correlated with their physicochemical properties calculated by the CACheTM program. The reactivities between amines and saccharides correlated well with their hydrogen bonding energies calculated by molecular mechanics.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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