ISSN:
0570-0833
Keywords:
Ketones
;
Hydrogen sulfide
;
Thiocarbonyl compounds
;
Chemistry
;
General Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Monoketones react with hydrogen sulfide in the presence of basic catalysts to give geminal dithiols or thioketones. β-Diketones are converted into monothiodiketones. α-Diketones can be selectively reduced by hydrogen sulfide in the cold in the presence of secondary or tertiary amines to give hydroxy-or mono-ketones.
Additional Material:
4 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/anie.196303701
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