ISSN:
0009-2940
Keywords:
Electron donor-acceptor cyclophanes
;
Charge-transfer compounds
;
Crown ethers
;
Oligooxaparacyclophane metal complexes, charge-transfer absorption of, crystal structures of
;
Cyclophanes, electron donor-acceptor
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The intramolecular oligooxa[3n.3]paracyclophane quinhy-drones 2-5 (with n = 3 to 6) were synthesized and their interactions with alkali and alkaline earth metal and mercury(II) ions were studied by electron absorption and NMR spectroscopy. Remarkable enhancements of the CT absorptions were observed by complexation with metal ions of the pentaoxa[15.3]paracyclophane quinhydrone 4 and the hexaoxa[18.3]paracyclophane quinhydrone 5 to the corresponding complexes 6a-e and 7, respectively. The various donor-acceptor orientations and the crown ether-like complexation in the calcium complex 6d, the mercury complex 6e and the barium complex 7 were determined by X-ray analysis. Moreover, the X-ray structures of the tetramethoxy-2,5,8-trioxa[9.3]paracyclophane 8a, a precursor of the quinhydrone 2, and of the pentaoxa[15.3](2,5)-p-benzoquinonophane 20, the product of oxidative demethylation of the quinhydrone 4, are given. For comparison with the cyclic quinhydrones acyclic analogs are also described.
Additional Material:
7 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19941271024
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