ISSN:
0009-2940
Keywords:
Aromatization
;
Electron transfer
;
Isotope effects
;
Indirect electrochemical oxidation
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Hydrogen Transfer Reactions, 171). - Electron-Transfer-Induced Aromatization of 1,4-Dihydronaphthalene by Tris(4-bromophenyl)aminiumyl IonsThe first step in the aromatization of 1,4-dihydronaphthalene (1) by the radical cation 2 of tris(4-bromophenyl)amine (3) is a rapid electron transfer in an equilibrium completely shifted to the side of the substrates. The deprotonation of the radical cation 7 of 1,4-dihydronaphthalene is rate-determining as shown by both cyclovoltagrams and isotope effects of deuterated hydrogen donors.
Additional Material:
4 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19911241137
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