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  • Engineering General  (1)
  • oxidation in oxygen  (1)
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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Oxidation of metals 39 (1993), S. 31-54 
    ISSN: 1573-4889
    Keywords: oxidation in oxygen ; Cu-Mn alloys ; reaction kinetics ; scale morphology
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Oxidation, in oxygen gas at atmospheric pressure, of copper-manganese alloys (Mn content less than 40 at.%) has been investigated between 600 and 850° C. The reaction kinetics, determined by thermogravimetry, follow a parabolic law for alloys having a low manganese content (less than 10 at.% Mn) but are more complex for higher concentrations, particularly in the first stages of the oxidation process. Whereas in the early stages of oxidation the kinetics are controlled by surface reactions which accompany the formation of the different oxide layers, they are later controlled by the diffusion of a mobile species when the parabolic law is followed. In this condition an apparent activation energy may be determined from the rate constants. These energies are of the order of 120–140 kJ mol−1, comparable with that for oxidation of pure copper (134 kj mol−1), indicating a similar oxidation mechanism. The oxide layers formed were identified by cross-checking results of X-ray diffraction, electron microprobe analysis, and from glow discharge spectrometry. External layers of CuO and Cu2O formed on alloys of lower manganese concentration, evolving towards one or several mixed copper-manganese oxide layers with increasing manganese content. Under the external layers, which were weakly adherent to the sample, an internal-oxidation layer formed, which was adherent and consisted of precipitates of Mn3O4/MnO dispersed in the copper lattice. For alloys richer in manganese (36 at. % Mn) and at temperatures above 850°C (20 at.% Mn), the internal-oxidation layer evolved into two zones: MnO particles beneath a zone of Mn3U4 particles.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 18 (1994), S. 1083-1105 
    ISSN: 0271-2091
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Solution methods are presented for the large systems of linear equations resulting from the implicit, coupled solution of the Navier-Stokes equations in three dimensions. Two classes of methods for such solution have been studied: direct and iterative methods.For direct methods, sparse matrix algorithms have been investigated and a Gauss elimination, optimized for vector-parallel processing, has been developed. Sparse matrix results indicate that reordering algorithms deteriorate for rectangular, i.e. M × M × N, grids in three dimensions as N gets larger than M. A new local nested dissection reordering scheme that does not suffer from these difficulties, at least in two dimensions, is presented. The vector-parallel Gauss elimination is very efficient for processing on today's supercomputers, achieving execution rates exceeding 2.3 Gflops the Cray YMP-8 and 9.2 Gflops on the NEC on SX3.For iterative methods, two approaches are developed. First, conjugate-gradient-like methods are studied and good results are achieved with a preconditioned conjugate gradient squared algorithm. Convergence of such a method being sensitive to the preconditioning, a hybrid viscosity method is adopted whereby the preconditioner has an artificial viscosity that is gradually lowered, but frozen at a level higher than the dissipation introduced in the physical equations. The second approach is a domain decomposition one in which overlapping domain and side-by-side methods are tested. For the latter, a Lagrange multiplier technique achieves reasonable rates of convergence.
    Additional Material: 15 Ill.
    Type of Medium: Electronic Resource
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