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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of thermal analysis and calorimetry 62 (2000), S. 633-645 
    ISSN: 1572-8943
    Keywords: Bi oxalate ; Ca oxalate ; coprecipitated BiSrCaCu oxalate ; Cu oxalate ; Fe oxalate ; Sr oxalate ; thermal decomposition
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract This work introduces results obtained during the preparation of a Bi-based material with superconducting properties by oxalate coprecipitation. The influence of Fe presence on the precursors thermal stability and on the superconducting phases formation mechanism are presented. The thermal decomposition and the stability in air of FeC2O4×2H2O and also of the components mixture were studied by DTA/TG. It was evidenced that iron oxalate decomposes at the lowest temperature compared to the decomposition temperatures of the individual oxalates. XRD, IR and TEM/ED studies were approached to investigate the individual oxalates and the mixture coprecipitates for the high-T c superconducting material synthesis.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1573-5036
    Keywords: compost ; phosphate fertilizer ; P-fixation capacity ; plant P uptake ; sesquioxic soils ; soil P availability
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract In sesquioxide-rich soils of tropical and subtropical areas and volcanic-ash soils with high levels of active Al(Fe), large amounts of phosphate fertilizers are needed to overcome their high P-fixation capacity (“quenching” strategy). A greenhouse pot experiment has been used to evaluate the effectiveness of city refuse compost (CRC) as a P-source for these variable-charge soils, compared to inorganic P. Mature CRC and K2HPO4 were applied at rates equivalent to 125, 250, 375, 500 and 625 kg P ha−1 to a ferrallitic soils from Tenerife Island (Andeptic Paleudult) with a high content in active Al+Fe (4.82%) and a high P-fixation capacity (87%). Perennial ryegrass (Lolium perenne L.) was grown in pots and plants were harvested at regular intervals after seedling emergence. CRC increases plant P concentration and soil labile-P proportional to the applied rate. The best results were obtained from a compost application of 30 t ha−1 equivalent-rate, after a residence time of at least three months. An important residual effect in the supply capacity of P in relation to the phosphate fertilizer was also observed. The relative agronomic effectiveness (RAE) in comparison to K2HPO4 was 66% after 6 months, considering P uptake + soil labile-P. The soil P-fixation capacity was significantly reduced from a compost application of 40 t ha−1 equivalent-rate. Competition in adsorption between organic ligands and phosphate, in combination with net mineralization of organic P in compost, might account for the high RAE value obtained. The main conclusion is that the city refuse compost could be a suitable P-amendment for resquioxic soils due to its high RAE, and the residual effect on P-supply. ei]H. Lambers
    Type of Medium: Electronic Resource
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