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Synthesis of 13-O-β-D-Glucopyranosylgibberellin A5 β-D-Glucopyranosyl Ester (1994)

Schneider, Gernot ; Schmidt, Jürgen

Weinheim : Wiley-Blackwell

Liebigs Annalen 1994 (1994), S. 1149-1151

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ISSN: 0170-2041

Keywords: Gibberellins ; Plant hormones ; Glucosyl conjugates ; Hormones ; Koenigs-Knorr reactions ; Chemistry ; Organic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: 13-O-β-D-Glucopyranosylgibberellin A5 β-D-glucopyranosyl ester (2a) was synthesized by base-catalyzed (triethylamine) reaction of gibberellin A5 13-O-β-D-glucopyranoside (4a) with α-acetobromoglucose followed by mild sodium methanolate deacetylation. Structures of the gibberellin A5 glucosyl conjugates were established by LSI-MS, ESI-MS, and 1H-NMR spectroscopy.

Additional Material: 2 Tab.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/jlac.199419941116

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