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  • 1
    ISSN: 1572-9605
    Keywords: Tl-Ba-Ca Cu-O superconductors ; HTSC/ferroelectric tunable microwave devices ; HTSC/ferroelectric multilayer structures
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: Abstract We describe materials deposition and characterization for a broad class of tunable microwave devices using high-temperature oxide superconductor and voltage-tunable oxide ferroelectric thin-film multilayer structures. Tl-Ba-Ca-Cu-O thin films deposited by sputtering ore-beam evaporation were patterned into microwave resonators, each consisting of two colinear microstrip line sections separated by a 5–20μm gap. A Ba0.1Sr0.9TiO3 (BST) layer was then over-coated to fill the gap. The relative dielectric constant of the BST films deposited by physical vapor or chemical techniques was measured at 77 K in the 1–10 MHz range and found to vary by up to a factor of 2 or more with voltage bias in test capacitor structures using Pt electrodes. In the BST (variable capacitor)-HTSC microwave resonator structures, the change of the relative dielectric constant of the BST under voltage bias has allowed variation of the fundamental frequency of up to 80 MHz in the 5–10 GHz range at 4 K. Film deposition by various techniques and associated structural, morphological, and electronic properties, as well as materials compatibility issues, are discussed.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-1: Polymer Chemistry 6 (1968), S. 1955-1963 
    ISSN: 0449-296X
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Poly-N-vinylcarbazole and its monomeric analog, i.e., N-ethylcarbazole, act as donors in charge transfer complexes with such electron acceptors as iodine, tetracyanoethylene, and tetracyanoquinodimethane. Poly-N-vinylcarbazole and N-ethylcarbazole are also capable of accepting electrons from an alkali metal such as sodium. A study of the spectral properties of both types of complexes showed that the monomer can both accept and donate electrons to a greater extent than the corresponding unit segment of the polymer chain. Equilibrium constants are presented for both cases, and estimates of the ionization potential of N-ethylcarbazole and related compounds are made from the characteristic charge transfer frequencies. Good agreement between these values and those calculated from molecular orbital theory is outlined.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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