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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Rheologica acta 31 (1992), S. 333-344 
    ISSN: 1435-1528
    Keywords: Iron oxide ; flocculated suspension ; linear viscoelasticity ; percolation ; cryo-scanning electron microscopy ; concentrated colloidal suspension
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Abstract Suspensions consisting of particles of colloidal dimensions have been reported to form connected structures. When attractive forces act between particles in suspension they may flocculate and, depending on particle concentration, shear history and other parameters, flocs may build-up in a three-dimensional network which spans the suspension sample. In this paper a floc network model is introduced to interpret the elastic behavior of flocculated suspensions at small deformations. Elastic percolation concepts are used to explain the variation of the elastic modulus with concentration. Data taken from the suspension rheology literature, and new results with suspensions of magnetic γ-Fe2O3 and non-magnetic α-Fe2O3 particles in mineral oil are interpreted with the model proposed. Non-zero elastic modulus appeared at threshold particle concentrations of about 0.7 vol.% and 0.4 vol.% of the magnetic and non-magnetic suspensions, respectively. The difference is attributed to the denser flocs formed by magnetic suspensions. The volume fraction of particles in the flocs was estimated from the threshold particle concentration by transforming this concentration into a critical volume concentration of flocs, and identifying this critical concentration with the theoretical percolation threshold of three-dimensional networks of different coordination numbers. The results obtained indicate that the flocs are low-density structures, in agreement with cryo-scanning electron micrographs. Above the critical concentration the dynamic elastic modulus G′ was found to follow a scaling law of the type G′ ∼ (Φ f -Φ f c ) f , where Φ f is the volume fraction of flocs in suspension, and Φ f c is its threshold value. For magnetic suspensions the exponent f was found to rise from a low value of about 1.0 to a value of 2.26 as particle concentration was increased. For the non-magnetic a similar change in f was observed; f changed from 0.95 to 3.6. Two other flocculated suspension systems taken from the literature showed a similar change in exponent. This suggests the possibility of a change in the mechanism of stress transport in the suspension as concentration increases, i.e., from a floc-floc bond-bending force mechanism to a rigidity percolation mechanism.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Medical & biological engineering & computing 17 (1979), S. 697-709 
    ISSN: 1741-0444
    Keywords: Impedance cardiograph ; Impedance waveforms ; Potential distribution
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Chemistry and Pharmacology , Medicine
    Notes: Abstract Various electrical-impedance methods have been proposed for the measurement of haemodynamic parameters noninvasively. For example, an impedance method is proposed for the measurement of cardiac output from the skin surface and is called impedance cardiography. However, there are many problems in the application of the impedance technique for the noninvasive measurement of haemodynamic parameters. One of them is the complicated structure of organs in the body. Another is the anomalous electrical properties of tissues. For these reasons, it is very difficult to obtain exact information about haemodynamics from the waveforms measured by the impedance cardiograph, in spite of the fact that the waveforms include much useful information. We can get useful information, if the relationships between the waveforms and the biomedical events in the subject are understood. In this paper, the relationships between the waveforms and the circulation of the blood are discussed theoretically and experimentally. The effects of the complicated structure of the organs and the anomalous electrical properties of tissues upon the waveforms are also discussed both theoretically and experimentally. For the analysis of the waveforms, it is very important to discuss (a) equipotential lines and potential distribution on the thorax, (b) the impedance or admittance between a pair of electrodes, (c) impedance or admittance changes due to blood circulation, (d) waveforms due to the pulsatile blood flow and (e) the effects of the complicated structure of organs upon the waveforms. From our results, it is concluded that: (a) the waveforms measured by an impedance cardiograph are affected not only by the change of blood volume in the aorta but also by that in various organs such as the heart and lungs. (b) the impedances measured by a pair of small electrodes separated by a short distance give useful information about the region in the vicinity of the electrodes (c) much valuable information will be available, if the relationships between the measurement results and the pulsatile blood flow are understood, and (d) by choosing an appropriate electrode arrangement, we may get much useful information about the blood circulation in the organs we want to investigate
    Type of Medium: Electronic Resource
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