ISSN:
0009-2940
Keywords:
Magnesium hydride, catalytically prepared
;
Hydromagnesation reactions
;
Magnesium, diorgano compounds, preparation from magnesium, hydrogen and 1-alkenes
;
Magnesium, diorgano compounds, application in syntheses
;
Magnesium, diorgano compounds, oxidation of
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
1-Alkenes are converted in high yields to the corresponding primary diorganomagnesium compounds by transition metalcatalyzed hydromagnesation reaction using catalytically prepared suspended (MgH2*) or dissolved magnesium hydride (MgH2*). The most active hydromagnesation catalysts have been found to be combinations of zirconium tetrahalides with MgH2* or MgH2*. The reaction is highly regio-and chemoselective. The diorganomagnesium compounds prepared in situ from magnesium, hydrogen, and 1-alkenes can be applied to the synthesis of organic and organometallic compounds just as Grignard compounds (Scheme 3, reaction 3-11). Dioctylmagnesium undergoes the growth reaction with ethene in the presence of quinuclidine and is oxidized by molecular oxygen in high yield to 1-octanol.
Additional Material:
5 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19931260616
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