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  • 1
    ISSN: 1572-8943
    Schlagwort(e): 1-butene isomerization ; M3+-substituted vanadyl phosphates ; structural characterization ; thermal characterization ; vanadyl phosphate
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract A set of new materials with general formula [M(H2O)]X(VO)1−XPO4·2H2O (M 3+=Al, Cr, Ga, Mn), isomorphous with layered tetragonal VOPO4·2H2O and having potential catalytic properties, have been characterized by TG and DTA, X-ray diffraction and surface acid strength. During heating the compounds transform in the monohydrated and anhydrous phases, all maintaining a layered structure, with a proper interlayer spacing. Catalytic tests performed with 1-butene show that theM 3+-vanadyl phosphates greatly improve the conversion of the olefine with respect to pure vanadyl phosphate.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Springer
    Journal of thermal analysis and calorimetry 52 (1998), S. 615-630 
    ISSN: 1572-8943
    Schlagwort(e): Fe3+-vanadyl phosphate ; NH3-TPD ; surface acidity ; TG/DTA ; vanadyl phosphate ; XRD
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Iron(III)-substituted vanadyl phosphate, [Fe(H2O)]0.20VO0.80PO4·2.25H2O (FeVOP), has been prepared and characterized by XRD and TG/DTA analyses. The new compound is isomorphous with layered tetragonal VOPO4·2H2O (VOP), but it possesses a lower interlayer distance. Information on the reactivity and surface acidity of both VOP and FeVOP has been obtained by NH3-TPD experiments. The hydrated materials adsorb high amounts of NH3 (up to 2 mmol g-1). Different ammonia-containing phases are formed, characterized by lower interlayer distances in comparison with the NH3-free parent compounds. NH3 is intercalated between the layers without displacement of water. The materials dehydrated by heat treatment at 450°C retain the layered structure but adsorb NH3 only on the external surface. A wide variety of acid sites, from weak to strong, was observed. A mechanism is proposed for the NH3- acid sites interaction. SEM micrographs of VOP and FeVOP are shown.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 3
    Digitale Medien
    Digitale Medien
    Springer
    Natural hazards 22 (2000), S. 225-268 
    ISSN: 1573-0840
    Schlagwort(e): Italy ; central Apennines ; active fault ; paleoseismology ; historical seismology ; seismic hazard
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik , Geographie , Geologie und Paläontologie
    Notizen: Abstract Quaternary tectonics and paleoseismologicalinvestigations have defined a reliable framework ofactive faults in the southern Umbria and AbruzziApennines. Two sets of NW–SE to NNW–SSE trending, 16to 33 km-long, normal and normal-oblique faults orfault systems have caused the displacement of LatePleistocene–Holocene deposits and landforms within theinvestigated sector. Available data on verticaloffsets indicate that both Late Pleistocene–Holoceneand Quaternary (since the later part of the EarlyPleistocene; 0.9–1 Ma) slip rates range between 0.4and 1.2 mm/yr (range 0.6–0.8 mm/yr preferred).Paleoseismological investigations show that recurrenceintervals for surface faulting events are alwaysgreater than 1,000 years and are usually greater than2,000 years. Both paleoseismological data andlong-term seismicity show that activation of theinvestigated faults may result in earthquakes ofM = 6.5–7.0. The extension rate across the two sets ofprimary faults ranges between 0.7 and 1.6 mm/yr.Horizontal seismic strain has been calculated to be0.5–0.6 mm/yr, based on the summation of the seismicmoment of M 〉 5.3 earthquakes which have affected theinvestigated area since 1200 AD. This value may belower than that inferred through geological data,probably because the seismological record reliable forthe addition of the seismic moments covers a too shorttime window (about 800 years) to be consideredrepresentative of the tectonic activity in theinvestigated area. This conclusion iscorroborated by the large recurrence intervalper fault (〉1,000–2,000 years) inferred frompaleoseismological analysis. A comparison of theactive-fault framework and historical-seismicitydistribution indicates that the entire eastern set ofactive faults has likely not been activated since 1000AD, thus indicating that the elapsed time since thelast activation for several faults of the investigatedarea may be greater than 1,000 years. In terms ofhazard, the highest probability of activation isrelated to the eastern set faults, due to theobservation that the elapsed time for some of thesefaults may be similar to the recurrence interval. Asan example, paleoseismological andarchaeoseismological data indicate that the elapsedtime for the Mt. Vettore and Mt. Morrone Faults may begreater than 1,650 and 1,850 years, respectively.These data may have significant implications for riskrelated to a number of towns in central Italy and tothe city of Rome. As for the latter, in fact,monumental heritage has suffered significant damagedue to earthquakes of M 〉 6.5 which originated in theinvestigated Apennine sector.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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