ISSN:
1588-2837
Keywords:
Strongly bound intermediates
;
mechanism of catalytic redox reactions
;
selective reduction of nitrogen oxides by hydrocarbons
;
methanol synthesis
;
Klaus reaction
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract The rate-limiting stage of heterogeneous catalytic redox reactions with participation of strongly bound surface species, such as nitrates, carbonates and sulfites, is the interaction of these heteroatomic oxidants with the reducing agents. It appears to be mainly determined by their bonding strength with the surface, being independent of the nature of the central atom (carbon, sulfur, nitrogen) and the energy of its bond with oxygen.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF02475810
Permalink