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  • Lissajous diagrams  (1)
  • blends  (1)
  • diffusion  (1)
  • 1
    ISSN: 1572-882X
    Keywords: cellulose ; magnetic resonance imaging ; diffusion ; structure
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Abstract NMR imaging and spatially resolved diffusometry have been used to study the distribution of water within swollen cellophane and measure its diffusion coefficient. Water concentration and diffusion coefficient were found to be essentially constant across most of the film thickness. However, significantly slower diffusion was indicated for water near the film surface (D = 0.5 × 10−9 m2 s−1) compared with water in the centre of the film (D = 0.88 × 10−9 m2 s−1). This was also reflected in lower T 2 values at the edge of the film indicating water with more restricted motion. These observations were interpreted in terms of dense surface regions of cellulose (skin) over a more porous interior (core).
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of thermal analysis and calorimetry 56 (1999), S. 1011-1016 
    ISSN: 1572-8943
    Keywords: crystallisation ; glass transition ; Lissajous diagrams ; modulated temperature power compensation differential scanning calorimetry ; polyethylene terephthalate/polycarbonate blends
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract A modulated temperature power compensated differential scanning calorimeter, MTDSC, has been built from a standard Perkin-Elmer DSC model-2 such that a computer generated voltage has been applied to induce a sinusoidal change in sample temperature superimposed on a linear heating rate. The effect of amplitude of the temperature fluctuation, modulation period and block temperature on the reversibility has been assessed from the Lissajous diagram of heat flow vs. sample temperature. From their reproducibility and symmetry the most effective conditions for operating the MTDSC has been deduced. The specific heat of sapphire has been measured using these operational conditions for comparison with conventional DSC. Phase separated blends of polycarbonate (PC) and polyethylene terephthalate (PET) have been analysed.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Journal of thermal analysis and calorimetry 56 (1999), S. 1081-1086 
    ISSN: 1572-8943
    Keywords: blends ; crystallisation kinetics ; hot stage microscopy ; polyether ether ketone ; polyether imide
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract PEI/PEEK blends have been prepared and analysed by DSC. The blends are compatible over the full composition range in that amorphous samples are transparent and exhibit a single Tg varying with composition between the limits of the two components. The crystallisation kinetics of PEEK from the blend melt has been measured by DSC but the technique is limited to blend compositions above 20% PEEK. The use of a polarised light microscope to measure crystallization kinetics and melting behaviour of blends with compositions as low as 2 and 5% PEEK is discussed. In general, since the extent rather than the rate of crystallization is measured directly, the polarised light microscopy extends the measurement to slower rates and so to a wider temperature range.
    Type of Medium: Electronic Resource
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