ISSN:
0749-1581
Keywords:
NMR
;
solid-state 13C NMR
;
titanium tetrachloride-ketone complexes
;
syn-anti isomerization
;
planar inversion
;
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The solid-state 13C NMR spectra of a series of titanium tetrachloride-ketone and titanium tetrachloride-ester complexes are presented. The kind of complexation is discussed. The activation energy and the mechanism (planar inversion) for the syn-anti isomerization at the oxygen atom was evaluated.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/mrc.1260330412
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