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Notes: Abstract A theoretical model was introduced for the evaluation of the boundary layer developed between the main phases during the preparation of unidirectional fiber composites. It has been shown that this thin layer influences considerably the physical properties of the composite. It was assumed that the physical properties of themesophase unfold from those of the hard-core fibers to those of the softer matrix. Thus, a multicylinder model was assumed improving the classical two-cylinder model introduced by Hashin and Rosen for the representative volume element of the composite. Based on thermodynamic phenomena appearing at the glass transition temperatures of the composite and concerning the positions and the sizes of the heat-capacity jumps there, as well as on the experimental values of the longitudinal elastic modulus of the composite, the extent of the mesophase and the mechanical properties of the composite may be accurately evaluated. This version of the model is based on a previous one concerning a multilayer model, but it is considerably improved in order to take into consideration, in a realistic manner, the physical phenomena developed in fiber reinforced composites.

Notes: Abstract Expressions for the evaluation of the transverse and longitudinal elastic moduli and the major Poisson ratio of unidirectional fiber composites are derived. The model described is based on the correct version of Kerner's model, which in our case is conveniently modified by introducing a mesophase layer between the fiber and the matrix in the representative volume element surrounding the typical fiber. The expression for the longitudinal elastic modulus derived in this paper, and the law of mixtures already presented in previous papers, give concordant results. Therefore, the law of mixtures, taking the mesophase also into account, and the two-term unfolding model for the mesophase are used for the evaluation of its extent and its properties. The model was applied to a glass filament-epoxy resin composite and its predictions were found to be in good agreement with the experimental data.

Notes: Abstract The size of the mesophase, which constitutes a boundary layer between fillers and matrix in composites, has been efficiently evaluated by the modified two-term unfolding model, which was based on delicate DSC measurements of the heat capacity jumps at the glass transitions of the composite and its constituent phases [1,2]. This model is now used to evaluate the mesophase along the whole viscoelastic spectrum of the composite, by making measurements of the storage and loss compliances or moduli of the composite and matrix and without making recourse to any other type of special measurement at the glass transition temperature of the substances. By applying this model the following important results were derived: i) Lipatov's empirical formula for defining the mesophase atT g was shown to yield reasonable results and ii) the evaluation of the size of mesophase over the entire viscoelastic spectrum was shown to remain almost constant and in conformity with the values defined by the other versions of the model. Extensive application of the experimental results of the literature indicated the mutual proof of the validity of these affine models.

Notes: Abstract A new relation for the prediction of the transverse shear modulus in unidirectional fiber composites has been derived. The theoretical results of this relationship are in better agreement with the experiments than those of other relations, existing in the literature. The discrepancies, which are observed among the theoretical predictions and the experimental values, are explained by the consideration of the boundary layers existing between the matrix and the fibers of the composite. A new model, which includes the intermediate phase between the matrix and the fiber, called the mesophase, is considered in order to take into account the above-mentioned layers.

Notes: Summary The spectral decomposition of the compliance, stiffness, and failure tensors for transversely isotropic materials was studied and their characteristic values were calculated using the components of these fourth-rank tensors in a Cartesian frame defining the principal material directions. The spectrally decomposed compliance and stiffness or failure tensors for a transversely isotropic body (fiber-reinforced composite), and the eigenvalues derived from them define in a simple and efficient way the respective elastic eigenstates of the loading of the material. It has been shown that, for the general orthotropic or transversely isotropic body, these eigenstates consist of two double components, σ1 and σ2 which are shears (σ2 being a simple shear and σ1, a superposition of simple and pure shears), and that they are associated with distortional components of energy. The remaining two eigenstates, with stress components σ3, and σ4, are the orthogonal supplements to the shear subspace of σ1 and σ2 and consist of an equilateral stress in the plane of isotropy, on which is superimposed a prescribed tension or compression along the symmetry axis of the material. The relationship between these superimposed loading modes is governed by another eigenquantity, the eigenangle ω. The spectral type of decomposition of the elastic stiffness or compliance tensors in elementary fourth-rank tensors thus serves as a means for the energy-orthogonal decomposition of the energy function. The advantage of this type of decomposition is that the elementary idempotent tensors to which the fourth-rank tensors are decomposed have the interesting property of defining energy-orthogonal stress states. That is, the stress-idempotent tensors are mutually orthogonal and at the same time collinear with their respective strain tensors, and therefore correspond to energy-orthogonal stress states, which are therefore independent of each other. Since the failure tensor is the limiting case for the respective σx, which are eigenstates of the compliance tensor S, this tensor also possesses the same remarkable property. An interesting geometric interpretation arises for the energy-orthogonal stress states if we consider the “projections” of σx in the principal3D stress space. Then, the characteristic state σ2 vanishes, whereas stress states σ1, σ3 and σ4 are represented by three mutually orthogonal vectors, oriented as follows: The ε3 and ε4 lie on the principal diagonal plane (σ3δ12) with subtending angles equaling (ω−π/2) and (π-ω), respectively. On the positive principal σ3-axis, ω is the eigenangle of the orthotropic material, whereas the ε1-vector is normal to the (σ3δ12)-plane and lies on the deviatoric π-plane. Vector ε2 is equal to zero. It was additionally conclusively proved that the four eigenvalues of the compliance, stiffness, and failure tensors for a transversely isotropic body, together with value of the eigenangle ω, constitute the five necessary and simplest parameters with which invariantly to describe either the elastic or the failure behavior of the body. The expressions for the σx-vector thus established represent an ellipsoid centered at the origin of the Cartesian frame, whose principal axes are the directions of the ε1-, ε3- and ε4-vectors. This ellipsoid is a generalization of the Beltrami ellipsoid for isotropic materials. Furthermore, in combination with extensive experimental evidence, this theory indicates that the eigenangle ω alone monoparametrically characterizes the degree of anisotropy for each transversely isotropic material. Thus, while the angle ω for isotropic materials is always equal to ωi = 125.26° and constitutes a minimum, the angle |ω| progressively increases within the interval 90–180° as the anisotropy of the material is increased. The anisotropy of the various materials, exemplified by their ratiosE L/2GL of the longitudinal elastic modulus to the double of the longitudinal shear modulus, increases rapidly tending asymptotically to very high values as the angle ω approaches its limits of 90 or 180°.

Notes: Summary  The spectral decomposition of the compliance, stiffness, and failure tensors for transversely isotropic materials was studied and their characteristic values were calculated using the components of these fourth-rank tensors in a Cartesian frame defining the principal material directions. The spectrally decomposed compliance and stiffness or failure tensors for a transversely isotropic body (fiber-reinf orced composite), and the eigenvalues derived from them define in a simple and efficient way the respective elastic eigenstates of the loading of the material. It has been shown that, for the general orthotropic or transversely isotropic body, these eigenstates consist of two double components, σ 1 and σ 2, which are shears (σ 2 being a simple shear and σ 1, a superposition of simple and pure shears), and that they are associated with distortional components of energy. The remaining two eigenstates, with stress components σ 3 and σ 4, are the orthogonal supplements to the shear subspace of σ 1 and σ 2 and consist of an equilateral stress in the plane of isotropy, on which is superimposed a prescribed tension or compression along the symmetry axis of the material. The relationship between these superimposed loading modes is governed by another eigenquantity, the eigenangle ω. The spectral type of decomposition of the elastic stiffness or compliance tensors in elementary fourth-rank tensors thus serves as a means for the energy-orthogonal decomposition of the energy function. The advantage of this type of decomposition is that the elementary idempotent tensors to which the fourth-rank tensors are decomposed have the interesting property of defining energy-orthogonal stress states. That is, the stress-idempotent tensors are mutually orthogonal and at the same time collinear with their respective strain tensors, and therefore correspond to energy-orthogonal stress states, which are therefore independent of each other. Since the failure tensor is the limiting case for the respective σ x-tensors, which are eigenstates of the compliance tensor S, this tensor also possesses the same remarkable property. An interesting geometric interpretation arises for the energy-orthogonal stress states if we consider the “projections” of σ x in the principal 3D stress space. Then, the characteristic state σ 2 vanishes, whereas stress states σ 1, σ 3 and σ 4 are represented by three mutually orthogonal vectors, oriented as follows: The ε 3- and ε 4-vectors lie on the principal diagonal plane (σ3∂12) with subtending angles equaling (ω−π/2) and (π− ; ω), respectively. On the positive principal σ3-axis, ω is the eigenangle of the orthotropic material, whereas the ε 1-vector is normal to the (σ3∂12)-plane and lies on the deviatoric π-plane. Vector ε 2 is equal to zero. It was additionally conclusively proved that the four eigenvalues of the compliance, stiffness, and failure tensors for a transversely isotropic body, together with value of the eigenangle ω, constitute the five necessary and simplest parameters with which invariantly to describe either the elastic or the failure behavior of the body. The expressions for the σ x-vector thus established represent an ellipsoid centered at the origin of the Cartesian frame, whose principal axes are the directions of the ε 1, ε 3- and ε 4-vectors. This ellipsoid is a generalization of the Beltrami ellipsoid for isotropic materials. Furthermore, in combination with extensive experimental evidence, this theory indicates that the eigenangle ω alone monoparametrically characterizes the degree of anisotropy for each transversely isotropic material. Thus, while the angle ω for isotropic materials is always equal to ω i =125.26° and constitutes a minimum, the angle |ω| progressively increases within the interval 90–180° as the anisotropy of the material is increased. The anisotropy of the various materials, exemplified by their ratios E L /2G L of the longitudinal elastic modulus to the double of the longitudinal shear modulus, increases rapidly tending asymptotically to very high values as the angle ω approaches its limits of 90 or 180°.

Notes: Summary The compliance tensor related to orthotropic media is spectrally decomposed and its characteristic values are determined. Further, its idempotent tensors are estimated, giving rise to energy orthogonal states of stress and strain, thus decomposing the elastic potential in discrete elements. It is proven that the essential parameters, required for a complete characterisation of the elastic properties of an orthotropic medium, are the six eigenvalues of the compliance tensor, together with a set of three dimensionless parameters, the eigenangles θ, ϕ and ω. In addition, the intervals of variation of these eigenangles with respect to different values of the elastic constants are presented. Furthermore, bounds on Poisson's ratios are obtained by imposing the thermodynamical constraint on the eigenvalues to be strictly positive, as specified from the positive-definite character of the elastic potential. Finally, the conditions are investigated under which a family of orthotropic media behaves like a transversely isotropic or an isotropic one.

Notes: Summary Materials with specific microstructural characteristics and composite structures are able to exhibit negative Poisson's ratio. This fact has been shown to be valid for certain mechanisms, composites with voids and frameworks and has recently been verified for microstructures optimally designed by the homogenization approach. For microstructures composed of beams, it has been postulated that nonconvex shapes (with reentrant corners) are responsible for this effect. In this paper, it is numerically shown that mainly the shape, but also the ratio of shear-to-bending rigidity of the beams do influence the apparent (phenomenological) Poisson's ratio. The same is valid for continua with voids, or for composites with irregular shapes of inclusions, even if the constituents are quite usual materials, provided that their porosity is strongly manifested. Elements of the numerical homogenization theory and first attempts towards an optimal design theory are presented in this paper and applied for a numerical investigation of such types of materials.

Notes: Abstract An accurate relationship for the shear modulus of particulates is derived based on the Kerner model, but not using its approximate relations. Furthermore, the model takes into account the existence of the mesophase layer between the inclusions and the matrix, which acts as a smooth transition boundary layer between constituent materials. By applying Christensen's field to the Kerner model, modified by introducing the mesophase, the new model is liberated from any inconsistencies. Experimental evidence and application to a glass particle-epoxy resin-matrix composite indicated the superiority of the model over previous ones.

Notes: Abstract In this paper the mesophase developed between main phases in fibrous composites was studied assuming that it constitutes a diffuse boundary. This type of mesophase is normally developed in polymer-polymer adjacent phases and it it useful for the study of modern composites disposing a coupling agent between main phases. At the high temperature of reaction of phases during the casting process both neighboring phases are partly liquified, allowing a two-way movement of elements of either phase whose intensity and extent depends on the particular diffusion characteristics of either phase and the affinities between them. The characteristics of this diffusion reaction were studied and their influence on the development and the properties of the adhesion between phases were established, especially for fiber composites. Interesting results were derived concerning the extent of the diffusive mesophase and its mechanical properties, as well as its contribution on the global mechanical behavior of the composite. Finally, the results were found to be in agreement with previously established models.