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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 53 (1994), S. 485-496 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A new route (“direct forming”) was developed for forming dense PBI shapes from PBI powder. The new process affords the possibility of automated PBI powder shaping (“cold compaction”) and densification in batches of multiple parts by a “powder-assisted hot isostatic pressing” process. Direct forming is a more productive alternative to hot compression molding. Two developments enable PBI direct forming: (1) the discovery that PBI powders that are porous and plasticized with moisture can be shaped by compaction at ambient temperatures (cold-compacted), and (2) a finding that cold-compacted shapes can be densified in large batches by a powder-assisted hot isostatic pressing. The porous PBI powder is formed from PBI in solution by a spray-precipitation process. When plasticized with moisture, this powder is cold-compactible to PBI shapes with densities up to 94% of that of ultimate density of PBI. These shapes, which have sufficient strength to be handled, are then further consolidated via powder-assisted hot isostatic pressing to shapes with excellent thermal and mechanical properties and densities of about 99% of the ultimate. © 1994 John Wiley & Sons, Inc.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 0021-9304
    Keywords: bonding-strength ; shear-strength ; simulated body fluid ; push-out measurement ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine , Technology
    Notes: This study was undertaken to evaluate the effect of coating characteristics on the mechanical strengths of the plasma-sprayed HA-coated Ti-6Al-4V implant system both in vitro and in vivo. Two types of HA coatings (HACs) with quite different microstructures, concentrations of impurity-phases, and indices-of-crystallinity were used. In vitro testings were done by measuring the bonding-strength at the Ti-6Al-4V-HAC interface, with HACs that had and had not been immersed in a pH-buffered, serum-added simulated body fluid (SBF). The shear-strength at the HAC-bone interface was investigated in a canine transcortical femoral model after 12 and 24 weeks of implantation. The results showed a bonding degradation of approximately 32% or higher of the original strength after 4 weeks of immersion in SBF, and this predominantly depended on the constructed microstructure of the HACs. After the push-out measurements, it was demonstrated that the HACs with higher bonding-strength in vitro would correspondingly result in significantly higher shear-strength at each implant period in vivo. Nevertheless, there were no substantial histological variations between the two types of HACs evaluated. The most important point elucidated in this study was that, among coating characteristics, the microstructure was the key factor in influencing the mechanical stability of the HACs both in vitro and in vivo. As a consequence, a denser HAC was needed to ensure mechanical stability at both interfaces. © 1997 John Wiley & Sons, Inc. J Biomed Mater Res, 37, 335-345, 1997.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Surface and Interface Analysis 26 (1998), S. 984-994 
    ISSN: 0142-2421
    Keywords: ToF-SIMS ; SIMS ; metal ; contamination ; Si ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: Volumetric relative sensitivity factors (RSFs) are determined for 52Cr, 56Fe and 58Ni in an O2+-formed silicon oxide using a 12 keV Ga+ primary ion beam, and the influence of matrix oxygen content on these RSF values is evaluated. A multivariate expression for Si2+-referenced RSF values as a function of oxygen content is developed. This expression indicates that 12 keV Ga+ ion beam RSF values for 52Cr, 56Fe and 58Ni in O2+-formed oxide at 1.0 nm depth are in excellent agreement with well-established 8 keV O2+ RSF values in a silicon matrix. Because calculated RSF values for O2+-formed oxide at 1.0 nm depth and native silicon oxide are almost equivalent, time-of-flight (ToF) SIMS metal RSF values and detection limits in native oxide for a Ga+ liquid metal ion source are predicted, using the well-established 8 keV O2+ RSF values for metals in a silicon matrix. Time-of-flight SIMS silicon surface detection limits of 5×106 to 5×108 atoms cm-2 @ 0.5 nm are predicted for most metals of interest to the semiconductor community. © 1998 John Wiley & Sons, Ltd.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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