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  • Polymer and Materials Science  (2)
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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 57 (1995), S. 953-960 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Different formulations were developed with an urethane oligomer combined with a number of reactive diluents with different functionalities such as N-vinylpyrrolidone (monofunctional), butanediol diacrylate (difunctional), tripropylene glycol diacrylate (difunctional), and trimethylolpropane triacrylate (trifunctional). The films were prepared with these formulations and cured under UV radiation in the presence of the photoinitiator Irgacura 184. Their properties were characterized. The effect of codiluents of low glass transition temperatures like ethyl hexyl acrylate and methoxyethyl acrylate on the properties of these films was studied. These formulations were then applied as thin coatings on the leather surface in order to study the improvement of the leather substrate. Both tensile strength and elongation of the treated leather increased. The gloss of the coated leather was also enhanced. Incorporation of a plasticizer into these systems substantially improved the rheological properties of the coated leather. © 1995 John Wiley & Sons, Inc.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 54 (1994), S. 309-315 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Polymer films were prepared with UV radiation from urethane acrylate oligomer (LR 8739) mixed with a photoinitiator (Irgacur 184) and a number of reactive diluents chosen from monofunctional monomers (such as N-vinyl pyrrolidone, ethylhexyl acrylate, methoxyethyl acrylate, and hydroxyethyl methacrylate), difunctional monomers (hexane dioldiacrylate, butanediol diacrylate, and tripropylene diacrylate), and a trifunctional monomer (trimethylol propane triacrylate). The optimum concentrations of the photoinitiator, oligomer, and diluents were determined. Various properties of the cured films such as pendulum hardness, gel content, swelling ability, tensile strength, and elongation at break were also determined. The glass transition temperatures (Tg) of the diluents were correlated with tensile properties and those of the film. © 1994 John Wiley & Sons, Inc.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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