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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of solution chemistry 18 (1989), S. 13-22 
    ISSN: 1572-8927
    Keywords: Excess volume ; viscosities ; Gibbs free energies of activation of flow ; DMSO ; alkanols
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Excess volumes and viscosities have been determined for DMSO + n-hexanol, + n-heptanol, + n-octanol, and + n-decanol at 40°C. The excess partial molar volumes V 1 E , changes in viscosities Δη, the parameter d of the Grunberg and Nissan expression, and excess Gibbs free energies of activation of flow ΔG * E have been calculated from the experimental data. All the excess volumes are positive over the whole composition range, with V E increasing with the length of the alkanol chain. V E results are discussed in terms of disruption of alkanol multimers, weakening of interactions between DMSO molecules, influence of interactions between components, and structural effects. The V E data have also been analyzed using the Prigogine-Flory-Patterson expression which separates V E into three contributions. Correlation is also observed between the sign of Δη and V E for all the mixtures studied.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1573-5036
    Keywords: Chloride and sulphate salinity ; Soybean yield ; Zn effect
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract A study was conducted in a screen house in pots on a sandy loam soil deficient in Zn. Salinity was induced by adding 44, 88 and 132 me/l of chloride and sulphate salts in the saturation extract. To these treatments, 0, 5 and 10 ppm Zn were added as ZnSO4·7H2O or Zn-EDTA. The results indicated that the yield of soybean shoot was lowest at the highest salinity level and highest at the lowest level. Shoot yield improved markedly with Zn application. Both sources of Zn were equally effective in augmenting crop yields. Yields were low in Cl-salinity when compared with equivalent levels of SO4-salinity. Application of ZnSO4·7H2O produced higher yields in SO4-dominant salinity. Zinc content increased and Zn uptake decreased with increase in Cl-salinity regardless of Zn sources. In SO4-salinity, ZnSO4·7H2O did not influence the Zn content, but uptake was suppressed with increase in SO4-salinity. Increasing rates of SO4-salinity enhanced Zn content in the presence of Zn-EDTA.
    Type of Medium: Electronic Resource
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