ISSN:
0009-2940
Keywords:
Thiatriazines, trichloro, preparation, structures
;
Calculations, MNDO
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
ChlorothiatriazinesFrom (ClSN)3 (1) and ClCN (2) 1,3,5-trichloro-1,3,2,4,6-dithiatriazine (ClCN)(ClSN)2 (3) was prepared in 26% yield. 3 reacts slowly further with excess 2 to give thiatriazine (ClCN)2(ClSN) (14) and triazine (ClCN)3 (16). A mechanism for the (ClSN)/(ClCN) exchange is proposed. The structures of 3, 14, and 16 have been determined by X-ray diffraction. The bonding situation in the system (ClSN)n(ClCN)3-n (n = 0 - 3) is discussed.
Additional Material:
5 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19931261207
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