ISSN:
0009-2940
Keywords:
Trifluorophosphine complexes
;
Vanadium complexes
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Communications on Metal Trifluorophosphine Complexes, 51. - Hexakis(trifluorophosphine)vanadium(0) - Synthesis, Chemical Properties, and Reactions[Na(diglyme)2][V(PF3)6] reacts with [PhN2][BF4] to afford the highly volatile, paramagnetic compound V(PF3)6 (1), while the reaction with [C7H7][BF4] yields [C7H7][V(PF3)6]. The metallocenium complexes [MCp2][V(PF3)6] (M=Fe, Co, Ni) are prepared by one-electron oxidation of MCp2 by 1.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19901230812
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