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  • hot corrosion  (3)
  • alloy oxidation  (2)
  • 1
    Digitale Medien
    Digitale Medien
    Springer
    Oxidation of metals 12 (1978), S. 273-291 
    ISSN: 1573-4889
    Schlagwort(e): eutectic alloys ; hot corrosion ; alumina-formers
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Maschinenbau
    Notizen: Abstract The hot-corrosion resistance of two γ/γ′-δ eutectic alloys, Ni-23.1 Nb-4.4 Al and Ni-19.7Nb-6Cr-2.5 Al, has been studied using three techniques: (1) a salt-coated test, in which the specimens are coated with a thin layer of Na2SO4 and oxidized; (2) the Dean rig test, in which salt is evaporated into the gas stream and allowed to condense continuously on the specimen; and (3) a sulfidation/oxidation test, in which the specimens were presulfidized for a short time in a H2/H2S mixture and then oxidized. The salt-coated test suggested that these alloys are generally quite resistant to sodium-sulfateinduced corrosion, although localized severe attack was sometimes encountered. The morphology of the corrosion products suggested that the mechanism of the attack was sulfidation/oxidation, and that salt fluxing mechanisms were relatively unimportant. In the Dean rig test it was shown that sodium chloride greatly increased the severity of attack, as has been shown earlier for alumina-forming superalloys.
    Materialart: Digitale Medien
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  • 2
    Digitale Medien
    Digitale Medien
    Springer
    Oxidation of metals 12 (1978), S. 439-449 
    ISSN: 1573-4889
    Schlagwort(e): alloy oxidation ; Ni-Cr alloys ; diffusion ; depletion zones
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Maschinenbau
    Notizen: Abstract Compositional changes in the alloy beneath scales have been examined for the oxidation of Ni-27.4%Cr and Ni-40.2% Cr in 1 atm oxygen in the temperature range 1073–1473°K. Calculations of the rate of approach of the interfacial alloy composition to a constant value are compared with experimental data. Theoretical chromium depletion profiles obtained using both a finite difference analysis and an analytical expression are shown to be essentially equivalent and in good agreement with experimental measurements. The consequences of alloy depletion for the scaling behavior, when the protective scale is ruptured, are discussed.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 3
    Digitale Medien
    Digitale Medien
    Springer
    Oxidation of metals 9 (1975), S. 45-67 
    ISSN: 1573-4889
    Schlagwort(e): oxidation ; hot corrosion ; nickel alloys ; composites
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Maschinenbau
    Notizen: Abstract The oxidation and hot corrosion behavior of a tungsten-fiber, reinforced Ni~ 20Cr alloy has been examined under the following exposure conditions: (a) pure oxygen at 1 atm pressure; (b) sulfidation in H2–10 %H2S; (c) presulfidation in H2–10 %H2S followed by oxidation in oxygen; and (d) oxidation in 1 atm oxygen after precoating with approximately 1 mg/cm2 of Na2SO4. Rapid oxidation of the tungsten fibers causes considerable distortion of the matrix and catastrophic degradation of the matrix follows. Inter diffusion between the matrix and the fibers is also important. During sulfidation, only the matrix forms sulfides, the fibers remaining unaffected. Consequently, presulfidation, although having a dramatic effect on the oxidation of the matrix does not have a damaging effect on the fibres. Equally, the presence of sodium sulfate is not critical, although severe oxidation of the exposed tungsten fibers is still observed.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 4
    Digitale Medien
    Digitale Medien
    Springer
    Oxidation of metals 12 (1978), S. 413-438 
    ISSN: 1573-4889
    Schlagwort(e): alloy oxidation ; diffusion ; alloy depletion profiles
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Maschinenbau
    Notizen: Abstract The assumptions involved in Wagner's original treatment of alloy depletion profiles are examined and found to be acceptable for many situations. Finite difference analyses do not result in profiles which are significantly different from those obtained by the much simpler analytical solution once steady-state parabolic growth is established. Consequently an analytical solution is preferred and its combination with the classical Wagner expression for scale growth leads to a unified description of alloy oxidation when only the least noble metal is oxidized. The description is tested for an Fe-27.4wt.% Cr alloy oxidized at 1273°K and agreement between theoretical and experimental results is satisfactory. Alternative treatments of alloy oxidation which require that there be no recession of the alloy-scale interface are discussed and it is concluded that this assumption is unnecessarily restrictive in many cases. Suggestions that the oxidation of austenitic steels is controlled by diffusion in the alloy and that an interfacial transfer step is of importance in determining the oxidation rate in some cases are shown to be based on invalid assumptions. An analytical solution to the diffusion equation is developed for the case when a phase change occurs in the alloy because of less noble metal depletion and an expression is also presented for the profile developed in the limiting case where depletion is determined by scale evaporation.
    Materialart: Digitale Medien
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  • 5
    Digitale Medien
    Digitale Medien
    Springer
    Oxidation of metals 22 (1984), S. 1-33 
    ISSN: 1573-4889
    Schlagwort(e): nickel ; sodium sulfate ; hot corrosion ; sulfurous gases
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Maschinenbau
    Notizen: Abstract The effects of SO2 and SO3 in the environment on the hot corrosion behavior of Ni in the temperature range 750–950°C has been studied. Below the melting point of Na2SO4 (884°C), rapid corrosion takes place by formation of a Na2SO4-NiSO4 melt, which can penetrate the porous oxide scale and give rise to sulfide information by coming in contact with the metal. The distribution of the sulfides depends on the SO2 level in the ambient gas. Continued corrosion occurs by a sulfidation-oxidation mechanism. At temperatures above the melting point of Na2SO4, accelerated degradation occurs via dissolution of the surface scale, followed by reprecipitation of the oxide in a nonprotective form.
    Materialart: Digitale Medien
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