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  • 1
    ISSN: 1572-9605
    Keywords: Surface ; superconductors ; decomposition ; electron microscopy
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: Abstract The surface chemistry of various Tl- and Hg-containing superconducting oxides has been studied by high resolution transmission electron microscopy. The mechanism of surface decomposition of these materials is discussed. High chemical reactivity of the Tl-O and Hg-O layers seem to be the main course of the decomposition. It is proposed that a surface substitution of Tl and Hg may stabilise the structures without losing superconducting properties.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of superconductivity 11 (1998), S. 143-144 
    ISSN: 1572-9605
    Keywords: Tl based high Tc superconductors ; synthesis ; Li doping ; microstructure ; magnetization
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: Abstract Polycrystalline Tl0.5Pb0.5Sr2Ca2Cu3LiyOx samples were synthesized. After processing under the same conditions, the Li-doped samples (y = 0.2) showed an average grain size three times larger than that of a typical undoped Tl,Pb-1223 sample (y = 0), and a 30% increase in sample density. The irreversibility line has significantly shifted to higher field with Birr ( 77K) ≅ 12 tesla. The intragranular critical current densities, estimated through the Bean model, are higher in Li-doped samples in temperatures below 77K and external magnetic fields greater than 2 tesla. The Tc,onset, of the Li-doped samples are lowered by typically 2-5 K compared with the undoped samples.
    Type of Medium: Electronic Resource
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