ISSN:
0887-624X
Keywords:
unsaturated polyester resin
;
poly(ethylene oxide)
;
hydrogen-bonding interaction
;
polymer blend
;
polymer morphology
;
crystallization kinetics
;
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Hydrogen-bonding interaction between the two components of the poly(ethylene oxide) (PEO)/oligoester (OER) blends and the PEO/crosslinked unsaturated polyester resin (PER) blends was found to be an important driving force to the miscibility of these polymer blends. Its strength is approximately as strong as the self-association of hydroxyl groups in either the pure OER or the pure PER. The crystallization kinetics and morphology of PEO in PEO/PER blends was remarkably affected by crosslinking. It was found that the overall crystallization rate of PEO in PEO/PER blends is larger than that in PEO/OER blends at the crystallization temperature investigated, which was considered to be the result of nucleation controlling mechanism. With decreasing PEO content, the regular shape of PEO spherulites turns irregular in PEO/OER blends, whereas in PEO/PER blends, the birefrigent spherulites turns into dendritic structures. Raising the crystallization temperature favors the formation of dendritic textures in PEO/PER blends. © 1997 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 35: 3169-3179, 1997
Additional Material:
10 Ill.
Type of Medium:
Electronic Resource
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