ISSN:
0268-2575
Keywords:
hydrogenation
;
alkylbenzenes
;
trickle-bed
;
Chemistry
;
Biochemistry and Biotechnology
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Process Engineering, Biotechnology, Nutrition Technology
Notes:
The liquid-phase hydrogenation kinetics of toluene, cumene and mesitylene was studied over an alumina-supported nickel catalyst in a laboratory scale trickle-bed reactor operating isothermally at temperature of 75-115°C and at hydrogen pressures of 20-40 bar. The experiments performed in the absence of intraparticular diffusion resistance showed that the catalyst deactivated rapidly at the initial stage of the experiment, after which a virtually stable level of the catalyst activity was attained. The systematic kinetic experiments carried out with a stable aged catalyst revealed that cumene and mesitylene at high concentrations retarded the hydrogenation rate, whereas such an effect was not observable for toluene. The results of the kinetic experiments were interpreted quantitatively with a reaction mechanism involving sequential addition of hydrogen to absorbed aromatic molecules.
Additional Material:
9 Ill.
Type of Medium:
Electronic Resource
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