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  • 1
    Electronic Resource
    Electronic Resource
    On the kinetic coupling and mechanism of aromatic ring hydrogenation (1998)
    Springer
    Reaction kinetics and catalysis letters 63 (1998), S. 47-51 
    Details
    ISSN: 1588-2837
    Keywords: Aromatic ring hydrogenation ; kinetics ; kinetic coupling
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Mechanism of catalytic hydrogenation of aromatic rings is discussed. The kinetic coupling concept is considered, which implies that a surface intermediate would be continuously “pumped down” from the equilibrium concentration level by the extremely fast subsequent step. It is demonstrated that due to thermodynamic constrains, the intermediate formation of cyclohexadiene is forbidden.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02475429
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