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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of superconductivity 13 (2000), S. 393-400 
    ISSN: 1572-9605
    Keywords: spin gap ; ion size ; magnetic doping ; resistivity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: Abstract Y(Ba1−x Gd x )2Cu3O7−δ compounds with x = 0 ∼ 0.15 are prepared using the solid reaction technique. With structure analysis by Rietveld refinement of x-ray diffraction, we find that Gd3+ ions prefer to occupy Y sites within lighter doping x ≤ 0.08 due to ion size effects, then begin partially to occupy Ba sites with doping content increasing, which gives vital influence on superconductivity and spin-gap properties. The magnetic doping effects of Gd3+ ions on spin-gap properties are investigated in detail by contrast of the distinguished behaviors between T* and T c, indicating that spin-gap temperature is not completely determined by the carrier density, but strongly dependent on the strength of interplane antiferromagnetic coupling. Finally, we propose an expression of in-plane resistivity dependent on the maximal width of spin-gap Δ0 to derive their values for different samples, which almost keep constant with the increase of Gd doping contents.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of superconductivity 9 (1996), S. 551-554 
    ISSN: 1572-9605
    Keywords: Iodometric titration ; superconductor ; indicator ; oxygen content
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: Abstract We present an improved double titration method for high-T c superconductors, in which the major step is adding KSCN as an indicator of the end point after the starch end point. By adding it, a greater amount of Na2S2O3 solution can be added after the starch end point, at least 0.12 ml. We found that adding KSCN can lead to precise measuring results and reduce the experimental error. The oxygen contents of two series of superconductors were determined by this approach. For YBa2Cu3O y , the errors are Δp∼0.003 and Δy∼0.005, which are lower than that of other reports.
    Type of Medium: Electronic Resource
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