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  • 11
    Electronic Resource
    Electronic Resource
    Springer
    Reaction kinetics and catalysis letters 41 (1990), S. 1-5 
    ISSN: 1588-2837
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Abstract Реакцию водяного газа исследовали на промышленном феррохромном катализаторе при 563–683 К. Данные скорости реакции подчиняутся кинетике первого порядка совместно с моделью диффузионного сопротивления для изотермических гранул. Параметры модели были определены с помошью нелинейных регрессий.
    Notes: Abstract The water-gas shift reaction was studied at 563–638 K over an industrial ferrochrome catalyst. The reaction rate data could be described by first order kinetics coupled to a diffusional resistance model for isothermal pellets. The model parameters were determined by simultaneous nonlinear regression.
    Type of Medium: Electronic Resource
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  • 12
    Electronic Resource
    Electronic Resource
    Springer
    Journal of clinical monitoring and computing 11 (1994), S. 63-70 
    ISSN: 1573-2614
    Keywords: chronic obstructive pulmonary disease ; nocturnal hypoxaemia ; sleep stages ; sleep study ; computer analysis ; thoracoplasty
    Source: Springer Online Journal Archives 1860-2000
    Topics: Computer Science , Medicine
    Notes: Abstract A computer-assisted method for the evaluation of sleep and breathing in patients showing chronic ventilatory impairment is described and validated. Signals of body and respiratory movements (static charge sensitive bed), air-flow (thermistors), oxygen saturation (SaO2), electro-oculography (EOG), and electromyography (EMG) were recorded overnight and analysed. Using the compressed output graphs of the data and a rapid scoring procedure, stages of wakefulness, non-REM (stages S1–S4) and REM sleep were identified. The procedure allowed analysis of oxygen saturation data separately for each sleep stage. For validation of the method, the sleep stages identified were compared with traditional sleep staging based on a simultaneous recording of EEG, EMG and EOG in 10 patients with chronic obstructive pulmonary disease (COPD) and in 15 patients treated by thoracoplasty (TPL) for pulmonary tuberculosis. The recordings were performed in a patient ward. In total, 32 night recordings were analysed. In the COPD patients, the sensitivity and specificity of the new method were 87% and 84% in detecting non-REM sleep, and 72% and 87% in detecting REM sleep, respectively. In the TPL patients the sensitivity and specificity were 93% and 89% with respect to non-REM sleep, and 92% and 94% in regard to REM sleep. The new method and traditional sleep staging provided closely similar quantitative estimates of the degree of sleep stage-(REM and non-REM) dependent arterial oxygen desaturation. It is concluded that the computer-assisted method, which is considerably less time consuming than traditional polysomnography, is reliable in studying sleep-related oxygenation in patients with chronic lung diseases.
    Type of Medium: Electronic Resource
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  • 13
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Journal of Chemical Technology AND Biotechnology 67 (1996), S. 265-275 
    ISSN: 0268-2575
    Keywords: hydrogenation ; alkylbenzenes ; trickle-bed ; Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Process Engineering, Biotechnology, Nutrition Technology
    Notes: The liquid-phase hydrogenation kinetics of toluene, cumene and mesitylene was studied over an alumina-supported nickel catalyst in a laboratory scale trickle-bed reactor operating isothermally at temperature of 75-115°C and at hydrogen pressures of 20-40 bar. The experiments performed in the absence of intraparticular diffusion resistance showed that the catalyst deactivated rapidly at the initial stage of the experiment, after which a virtually stable level of the catalyst activity was attained. The systematic kinetic experiments carried out with a stable aged catalyst revealed that cumene and mesitylene at high concentrations retarded the hydrogenation rate, whereas such an effect was not observable for toluene. The results of the kinetic experiments were interpreted quantitatively with a reaction mechanism involving sequential addition of hydrogen to absorbed aromatic molecules.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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