ISSN:
1600-5368
Source:
Crystallography Journals Online : IUCR Backfile Archive 1948-2001
Topics:
Chemistry and Pharmacology
,
Geosciences
,
Physics
Notes:
The title compound, C35H54N2, crystallizes as the E/Z and E/E isomers. There are two independent molecules in the crystal; the first occupies a general position, adopts a non-symmetrical conformation and represents the E/Z isomer with respect to the C=N bonds; the second exhibits exact C2 symmetry (E/E isomer). The observed bond lengths and disposition of the H atoms in both molecules are consistent with a diimine. This contrasts with the related compound 2-(2,6-diisopropylphenylamino)-4-(2,6-diisopropylphenylimino)-2-pentene, which crystallizes as the imine–enamine tautomer.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1107/S1600536801011783
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