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  • 1
    Electronic Resource
    Electronic Resource
    Linear prediction and resolution enhancement of complex line shapes in two-dimensional electron-spin-echo spectroscopy (1986)
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 85 (1986), S. 63-67 
    Details
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: A new type of two-dimensional electron-spin-echo (2D-ESE) spectroscopy was recently shown to be useful for studying slow molecular motions in liquids. A recently developed method of spectral enhancement based upon linear prediction with singular value decomposition (LPSVD) is applied in the present work to dramatically improve the signal-to-noise ratio and to correct for finite dead time in the data from this 2D-ESE experiment. This permitted a more accurate comparison between theory and experiment. Good agreement is now obtained with a model of nearly isotropic Brownian motion for tempone in glycerol/water solvent.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1063/1.451595
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