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  • 1
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: Carbides Gd2Fe17Cx with composition up to x=2 were successfully prepared. The single phase Gd2Fe17Cx (x=1.5, 2.0) carbides with higher carbon concentration were first obtained by the melt quenching technique. 57Fe Mössbauer spectra of all compounds were measured and the results show that the average hyperfine field and isomer shift increase with increasing carbon concentration in the studied composition range. The effects of the interstitial carbon atoms on the hyperfine parameters are discussed. According to the result of the quadrupole splitting, the easy magnetization direction at room temperature for all carbides was determined.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 66 (1995), S. 2343-2345 
    ISSN: 1077-3118
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: Single phase γ'-Fe4N type (Fe1−xNix)4N compounds (0≤x≤0.6) have been synthesized by heating iron-nickel oxalates under a mixture stream of NH3 and H2. The compounds were investigated by x-ray diffraction and Mössbauer spectroscopy. The results confirm that the lattice constants decrease with increasing content of nickel. Compared with the same compositional Fe1−xNix alloys, the average expansion of the unit cell (δV/V) is 16.7% for γ-Fe-Ni alloys. The Mössbauer study shows that the substitution of nickel atoms for iron atoms has a tendency to locate at the corner sites. When x=0.5, all of the corner sites are completely occupied by nickel atoms. © 1995 American Institute of Physics.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 3
    Digitale Medien
    Digitale Medien
    Springer
    Journal of materials science 30 (1995), S. 4857-4860 
    ISSN: 1573-4803
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Maschinenbau
    Notizen: Abstract Single phase γ′-Fe4N type (Fe1−xNix)4N compounds (0 ≤ x ≤ 0.6 have been synthesized for the first time by controlled heat treatment of iron-nickel oxalates in a gaseous flow of NH3 xand H2. The preparation processes were investigated using differential scanning calorimetry (DSC), X-ray diffraction and Mössbauer spectroscopy. The results confirmed that annealing of oxalates in the NH3 and H2 atmosphere included the processes of dehydration, decomposition and reduction, nitrogenation and thermal decomposition of the nitrides. The decomposition and reduction occur simultaneously. The final products depend on the flow rate ratio of NH3 ∶ H2 and the annealing temperature. The formation conditions for the single phase γ′-Fe4N type (Fe1−xNix)4N compounds are related to the nickel concentration, with increasing nickel content, the nitrogenation temperature decreased, in contrast the flow rate ratio of NH3∶ H2 increased.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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