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  • 1
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 85 (1999), S. 5702-5704 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A new multinuclear metals condensation product (polymer C) was prepared by a condensation reaction between bis(oxamide oximato)nickel and 1,1′-dicarbaldehydeferrocene. Its structure was investigated by using elemental analysis, Fourier-transform infared, x-ray diffraction, and thermogravimetric analysis techniques. All these results show that the polymer is a three-dimensional layer, large π-conjugated part order structure and its initial decomposition temperature is about 230 °C. The magnetic susceptibility was measured from 5 to 160 K by a superconducting quantum interference device magnetometer under the applied magnetic field of 10 kOe. The plot of 1/χM vs T is linear in the range of 5–30 K, but deviates from the line above 30 K. The Weiss constant θ calculated according to the equation χM=C/(T−θ) in the 5–30 K was −2.1 K, indicating presence of a weak antiferromagnetic coupling between the most near neighboring two metal ions. The polymer C can also easily complex with metal ion Cu2+, but is difficult with Mn2+. © 1999 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Carbides Gd2Fe17Cx with composition up to x=2 were successfully prepared. The single phase Gd2Fe17Cx (x=1.5, 2.0) carbides with higher carbon concentration were first obtained by the melt quenching technique. 57Fe Mössbauer spectra of all compounds were measured and the results show that the average hyperfine field and isomer shift increase with increasing carbon concentration in the studied composition range. The effects of the interstitial carbon atoms on the hyperfine parameters are discussed. According to the result of the quadrupole splitting, the easy magnetization direction at room temperature for all carbides was determined.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 30 (1995), S. 3909-3912 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Under isothermal and linear heating conditions, the thermal stability of the three-dimensional metallic glass Ni68B21Si11, produced by rapid quenching of the denucleated melt (RQDM), has been systematically studied using PE DSC7 differential scanning calorimetry in relation to denucleation of liquid alloy prior to rapid quenching, pre-anneal treatment of amorphous specimens, and cooling rate. The following results were observed. First, the thermal stability of metallic glass prepared by RQDM is obviously enhanced because of the removal of pre-existing nuclei in advance. This is substantiated by the experimental data showing that the projected life of three-dimensional metallic glass Ni68B21Si11 is increased by an order of magnitude at 400 K. Secondly, pre-anneal treatment of the amorphous alloy leads to a reduction of temperature for the onset of crystallization,T x, and crystallization heat, ΔH. Finally, quenching rates have little effect on the thermal stability of amorphous alloys.
    Type of Medium: Electronic Resource
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