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Utilization of Macroporous Polymer Containing Phenylboronic Acid Groups in the solid- phase synthesis (1988)

Sarhan, A. ; Ali, M. M. ; Abd El-Al, M. Y.

New York, NY : Wiley-Blackwell

Journal für Praktische Chemie/Chemiker-Zeitung 330 (1988), S. 71-78

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Details

ISSN: 0021-8383

Schlagwort(e): Chemistry ; Organic Chemistry

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie

Notizen: Ethylene glycol (4-vinylphenyl-)-boronate (2) was copolymerized with technical divinylbenzene to highly crosslinked macroporous polymer (P2). On treatment of P2 with methanol/water, 75% of the polymer-bound ethylene glycol could be split-off, under formation of the desired polymer (P1) with free phenylboronic acid groups. The utility of P1 in the solid-phase synthesis, for instance its conversion to polymer-supported phenol, and as polymer-supported protecting group for diols was investigated.

Zusätzliches Material: 2 Tab.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1002/prac.19883300114

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