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  • 1
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 90 (1989), S. 3831-3837 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: We have carried out stochastic trajectory simulations of the scattering of argon clusters, Arn, n=5 to 26, from a Pt(111) surface. At incident energies of 0.1 and 0.5 eV per atom, the clusters fragment almost completely into individual atoms. Some atoms remain trapped on the surface, but the majority scatter. For the larger clusters, the angular distributions of the scattered atoms peak near the surface tangent, and are almost independent of the incident angle. The mean kinetic energy of atoms is largest for those scattered near the surface tangent, and decreases as the scattering angle approaches the surface normal. These trends are in qualitative accord with the results of experimental studies of cluster scattering from surfaces. A multiple binary collision mechanism involving atom–atom collisions within the cluster as well as atom–surface collisions is responsible for this behavior.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 88 (1988), S. 3376-3384 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: We have carried out stochastic trajectory calculations of the scattering of small argon clusters, n=1,2,3, and 5, from a Pt(111) surface at incident energies of 0.1 and 0.5 eV per atom. We employed a 6 by 6 by 2 layer slab of platinum atoms with periodic boundary conditions imposed in the x and y (surface plane) directions. We applied local friction and white random forces in the z (surface normal) direction to the bottom surface layer to maintain the proper temperature and to account for energy transfer with the bulk. We assumed Lennard-Jones interactions for Ar–Ar and Ar–Pt with realistic parameters. We have found that the scattering of small clusters from surfaces exhibits a very different behavior from the scattering of individual atoms or molecules. At the collision energies considered, most clusters fragment into atoms upon impact with the surface, but a surprising number survive either partially or totally intact. Angular distributions of the fragmented monomers are much broader than those of surviving clusters. The average energy of the fragmented monomers increases with scattering angle, the reverse of the "hard-cube'' trend for atoms scattering from surfaces. In addition, cluster scattering is associated with an enhanced trapping probability and enhanced initial lateral mobility of the trapped species in comparison to individual atom scattering. A sequential binary collision model invoking gas–surface and gas–gas collisions is suggested to account for these results.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1520-510X
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Science Inc
    Journal of the American Ceramic Society 88 (2005), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Tetragonal ZrO2 (t-ZrO2) nanoparticles (diameter: ca. 10 nm; BET-specific surface area: 100 m2/g) are hydrothermally prepared via crystallization of 1,12-diaminododecane (DADD)-hydrous zirconia gels at 230°C for 3 days. The volume content of monoclinic phase is ca. 0.1. The surface-adsorbed hydrocarbon layer (ca. 3 wt%) is observed by FTIR and TGA. They account for the formation of our t-ZrO2 nanoparticles with high-phase purity.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 298 (1982), S. 746-747 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] The success of expeditions in Pakistan1 and Europe2 in recovering late Miocene hominoids has stimulated fossil hunting in terrestrial deposits throughout southern Asia. Chinese scientists have recovered remarkably complete fossils from a site near Lufeng, Yunnan. Diverse rodents are frequently ...
    Type of Medium: Electronic Resource
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  • 6
    ISSN: 1572-879X
    Keywords: glycol ; oxidative dehydrogenation ; silver-phosphorus catalyst
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract A phosphorus-modified electrolytic silver catalyst was prepared and used as catalyst in the oxidative dehydrogenation of glycoto glyoxal. The yield of glyoxal was observed as high as 82% at 98% conversion for the Ag-P catalyst, while 62% at 89% conversion for the pure electrolytic silver. The formation of the surface compounds between the phosphorus additives and the silver surface was demonstrated by means of XPS and SEM. It caused the decrease of the surface concentration of atomic oxygen species, and restrained the decomposition and total oxidation of adsorbed glycol to C1 products.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Catalysis letters 2 (1989), S. 35-41 
    ISSN: 1572-879X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract We have carried out studies of hydrogen adsorption on sulfur covered Ru(001) and observed two weak hydrogen adsorption states with desorption temperatures at 135 K and 265 K. The existence of these hydrogen states is attributed to the long-range electronic effects of sulfur adatoms in addition to their site blocking, and also to the repulsive interactions among coadsorbed hydrogen within a p(2×2)-S structure.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Key engineering materials Vol. 353-358 (Sept. 2007), p. 1322-1325 
    ISSN: 1013-9826
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: 55vol% TiB2P/2024Al composite was fabricated by squeeze casting technology, and theeffect of heat treatment on mechanical properties of the composites was studied by means of hardnessmeasurement, scanning electron microscopy (SEM), transmission electron microscopy (TEM) andtensile testing etc. Results show that heat treatment has remarkable influence on the hardness and thetensile strength of the composites. For TiB2P/2024Al composites, the composites aged at 130°C for 5hcan obtain the highest hardness, and the composites peak-aged at 160°C and aged at 190°C for 24hcan obtain the higher tensile strength, which is due to the type of precipitates in the composites.Considering the experimental error, heat treatments has no obvious effect on elastic modulus of theexperimental composite
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Key engineering materials Vol. 353-358 (Sept. 2007), p. 1675-1678 
    ISSN: 1013-9826
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Improved corrosion resistance of carbon fiber reinforced aluminum (Cf/Al) matrixcomposites can be achieved by applying appropriate coatings, and the electroless platingnickel-phosphor (Ni-P) coatings on the Cf/Al composites was provided in this paper. It has beenfounded that the pretreatment with zinc dipping solution for the electroless plating Ni-P can beapproved perfect coatings on the Cf/Al composites. The EDS lines scanning results that the lengthof Ni-P coating is about 12 +m. In zinc dipping bath, matrix Al alloy surface could catch hold ofaction points for depositing Ni-P with substitution reaction, however, carbon fibers surface onlyhave adsorption action points from zinc dipping bath, then, Ni-P alloys could deposit on the Alsurface or carbon fibers. The uncoated and coated composites samples immersed in 3.5 wt % NaClsolution to contrast. The pitting corrosion behavior of the uncoated composites destroyed materials,therefore, the coated sample appeared pitting only on the surface. The corrosion resistancemechanisms of Ni-P coatings came from inhabiting the formation of the classical galvanic corrosion,additionally, the Ni-P coating was amorphous structure, there was not grains boundary which issensitive for the corrosion reaction, so the corrosion resistant of Cf/Al composites were improved
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Key engineering materials Vol. 353-358 (Sept. 2007), p. 1459-1462 
    ISSN: 1013-9826
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: High reinforcement content TiB2/2024Al composites (Vp=55, 65%) were fabricated bysqueeze casting technology, and their microstructures as well as mechanical properties underquasi-static and dynamic loading were evaluated. For 55 vol.% TiB2/Al composite, the bendingstrength and elastic modulus were as high as 623.5MPa and 218.1GPa. When compressed at a strainrate of 1050s-1, both composites exhibited a higher compressive flow stresses and compressivemoduli than those under quasi-static loading. The micro-damage of high reinforcement contentcomposites was mostly dominated by the large particle cracking. In addition, some evidence ofaluminum alloy melting was observed on the fracture surfaces of dynamic compression, it wasascribed to the adiabatic heat accumulated in a local region transferred by plastic work
    Type of Medium: Electronic Resource
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