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  • 1
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 2512-2516 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The growth of Ge(001) by molecular-beam epitaxy at temperatures Ts between 20 and 100 °C, and deposition rates of 0.5 and 1 A(ring) s−1, was investigated using a combination of in situ reflection high-energy electron diffraction and post-deposition cross-sectional transmission electron microscopy. All films consisted of three zones beginning with a defect-free epitaxial layer of thickness t1 in which ln(t1)∝(1/Ts). The second zone was a narrower intermediate layer containing {111} stacking faults and microtwins, while the third zone was amorphous. An atomistic growth model is proposed to explain the observed morphological breakdown during low-temperature growth.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 68 (1990), S. 617-620 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The noncontact transient grating technique under constant electron-hole pumping to the density 4×1019 cm−3 was used to characterize the ambipolar diffusion coefficient Da in Si:Al, Si:In, and Si:Sb molecular-beam-epitaxy-grown layers. Da was found to be almost constant at a value of ≈8 cm2/s up to an equilibrium carrier density of 2×1019 cm−3 in the layer and was independent of the doping type. At higher doping density, evidence for a sharp increase in Da was observed. For example, Da increased to a value of 20 cm2/s at a doping density of about 1020 cm−3. The Da behavior is in reasonable agreement with results of the high-density ambipolar diffusion theory of Young and van Driel and is incompatible with majority-carriers diffusion coefficients according to the formula Da = 2DnDp/(Dn + Dp). An explanation for this behavior is given.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 69 (1991), S. 6394-6399 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The crystallization of amorphous Si induced by Al during heat treatment has been investigated by cross section and plan view transmission electron microscopy. The lowest temperature of Al induced crystallization of amorphous Si was found to be 440 K. The crystallization temperature, however, depends on the thickness of Al layers in layered structures and on the concentration of Al in co-deposited layers below 1-nm-layer thickness and 15 at.% of Al concentration, respectively. Al-induced crystallization in layered structures starts at the Al/amorphous Si interfaces and is located close to them. The amount of crystallized Si depends on the quantity of Al and on the temperature and increases with them. The mechanism of crystallization involves intermixing of Al with Si and the formation of an alloy of high metal concentration in the amorphous/crystalline interface. When the formation of this alloy is not assured due to low Al concentration, then crystallization does not start or the process of crystallization stops. In Al induced crystallization the nucleation of polycrystalline Si grains rather than their crystal growth is affected.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 70 (1991), S. 1471-1474 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Carrier dynamics in strained Si1−xGex layers and Si/Si1−xGex superlattices, grown by molecular beam epitaxy with different Ge concentrations, were investigated by a transient grating method. The ambipolar diffusion coefficient Da of carrier transport parallel to the layer plane was determined at high-density carrier excitation. An increase to Da values by a factor of up to 1.5 was observed for the strained alloy films compared to the value for moderately doped molecular beam epitaxy silicon layers. This is the first experimental evidence for enhanced performance of parallel carrier transport in Si1−xGex alloy layers.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 77 (1995), S. 3067-3076 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: B-doped Si(001)2×1 films were grown on Si(001) substrates by gas-source molecular beam epitaxy using Si2H6 and B2H6. B concentrations CB (5×1016–5×1019 cm−3) were found to increase linearly with increasing flux ratio JB2H6/JSi2H6 (9.3×10−5–2.5×10−2) at constant film growth temperature Ts (600–950 °C) and to decrease exponentially with 1/Ts at constant JB2H6/JSi2H6 ratio. The B2H6 reactive sticking probability ranged from (approximately-equal-to)6.4×10−4 at Ts=600 °C to 1.4×10−3 at 950 °C. The difference in the overall activation energies for B and Si incorporation at Ts=600–950 °C is (approximately-equal-to)0.34 eV. A comparison of quantitative secondary-ion mass spectrometry (SIMS) and temperature-dependent Hall-effect measurements showed that B was incorporated into substitutional electrically active sites over the entire B concentration range investigated. SIMS B depth profiles from modulation-doped samples were abrupt with no indication of surface segregation to within the instrumental resolution limit and initial δ-doping experiments were carried out. Structural analysis by in situ reflection high-energy electron diffraction combined with post-deposition high-resolution plan-view and cross-sectional transmission electron microscopy showed that all films were high-quality single crystals with no evidence of dislocations or other extended defects. Temperature-dependent (20–300 K) hole carrier mobilities were equal to the best reported bulk Si:B values and in good agreement with theoretical maximum values. © 1995 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 78 (1995), S. 6027-6032 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Secondary-ion-mass spectrometry (SIMS) was used to determine the concentration and depth distribution of B incorporated into Ge(001)2×1 films grown on Ge(001) substrates by gas-source molecular-beam epitaxy using Ge2H6 and B2H6. B concentrations CB (3×1016–4×1019 cm−3) were found to increase linearly with increasing flux ratio JB2H6/JGe2H6 (8.2×10−3–1.7) at constant film growth temperature Ts (300–400 °C) and to increase exponentially with 1/Ts at constant JB2H6/JGe2H6 ratio. The difference in the overall activation energies for B and Ge incorporation over this growth temperature range is (approximately-equal-to)0.22 eV while B2H6 reactive sticking probabilities ranged from 8×10−4 at 300 °C to 2×10−5 at 400 °C. SIMS depth profiles from B modulation-doped samples and two-dimensional δ -doped samples grown at Ts〈350 °C were abrupt to within instrumental resolution with no indication of surface segregation. Structural analysis by in situ reflection high-energy electron diffraction combined with postdeposition high-resolution plan-view and cross-sectional transmission electron microscopy showed that all films were high-quality single crystals with no evidence of dislocations or other extended defects. B doping had no measurable affect on Ge deposition rates. © 1995 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 77 (1995), S. 1504-1513 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The growth rates RGe of epitaxial Ge films deposited on Ge(001)2×1 and Si(001)2×1 substrates from Ge2H6 by gas-source molecular beam epitaxy were determined over a wide range of temperatures Ts (300–800 °C) and impingement fluxes JGe2H6(0.1–1×1016 cm−2 s−1). Steady-state RGe(Ts, JGe2H6) curves were well described at both low and high growth temperatures (Ts≤325 °C and Ts(approximately-greater-than)500 °C) using a model based upon dissociative Ge2H6 chemisorption followed by a series of surface decomposition reactions with the rate-limiting step being first-order hydrogen desorption from Ge monohydride for which the activation energy was found to be 1.56 eV. At intermediate temperatures, however, experimental RGe results exhibited a large positive deviation from model predictions due, as demonstrated by temperature programmed desorption measurements and transmission electron microscopy (TEM) observations, to kinetic surface roughening. Extensive (113) faceting resulted in both an increase in the number of active surface sites and higher reactive sticking probabilities. With increased growth temperatures, the facets became more rounded and film surfaces appeared sinusoidal in cross section. The zero-coverage Ge2H6 reactive sticking probability on Ge(001) in the high-temperature flux-limited regime was found to be 0.052, more than two orders of magnitude higher than that for GeH4. In situ reflection high-energy electron diffraction and post-deposition TEM examinations showed that Ge films deposited on Ge(001) at Ts≤325 °C grew in a layer-by-layer mode exhibiting a smooth flat surface. © 1995 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 76 (1994), S. 1884-1888 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The growth rates RSi of Si films deposited on Si(001)2×1 from Si2H6 by gas-source molecular-beam epitaxy were determined as a function of temperature Ts (500–950 °C) and impingement flux JSi2H6 (0.3–7.7×1016 cm−2 s−1). RSi (Ts,JSi2H6) curves were well described using a model, with no fitting parameters, based upon dissociative Si2H6 chemisorption followed by a series of surface decomposition reactions with the rate-limiting step being first-order hydrogen desorption from Si monohydride. The zero-coverage Si2H6 reactive sticking probability in the impingement-flux-limited growth regime was found to be 0.036, more than two orders of magnitude higher than that for SiH4. B doping concentrations (CB=5×1016–3×1019 cm−3) from B2H6 increased linearly with increasing flux ratio JB2H6/JSi2H6 at constant Ts and decreased exponentially with 1/Ts at constant JB2H6/JSi2H6. Secondary ion mass spectrometry analyses of modulation-doped samples revealed sharp profiles with no detectable B segregation. Hole mobilities in uniformly doped samples were equal to bulk values.
    Type of Medium: Electronic Resource
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  • 9
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A single-grid ultra-high-vacuum-compatible ion source was used to provide accelerated In+-dopant beams during Si(100) growth by molecular-beam epitaxy. Indium incorporation probabilities σ, determined by secondary ion mass spectrometry, in films grown at Ts=800 °C were too low to be measured for thermal In (σIn was 〈3×10−5 at Ts〉550 °C) . However, for accelerated In+ doping, σIn+ at 800 °C ranged from 0.03 to ∼1 for In+ acceleration energies EIn+ between 50 and 400 eV. Temperature-dependent Hall-effect and resistivity measurements were carried out on In+-doped Si films grown at Ts =800 °C with EIn+=200 eV . Indium was incorporated substitutionally into electrically active sites over a concentration ranging from 2×1015−2×1018 cm−3, which extends well above reported equilibrium solid-solubility limits. The acceptor-level ionization energy was 156 meV, consistent with previously published results for In-doped bulk Si. Room-temperature hole mobilities μ were in good agreement with the best reported data for B-doped bulk Si and were higher than previously reported values for annealed In-implanted Si. Temperature-dependent (77–400 K) mobilities μ(T) were well described by theoretical calculations, with no adjustable parameters, including lattice, ionized-impurity, neutral-impurity, and hole-hole scattering. Lattice scattering was found to dominate, although ionized-impurity scattering was still significant, at temperatures above ∼150 K where μ varied approximately as T−2.2 . Neutral-impurity scattering dominated at lower temperatures. Plan-view and cross-sectional transmission electron microscopy observations showed no indications of dislocations or other extended defects. Considering the entire set of results, there was no evidence of residual ion-bombardment-induced lattice damage.
    Type of Medium: Electronic Resource
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  • 10
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A single-grid broad-beam ion source was used for low-energy (50–500 eV) accelerated In+ ion beam doping during growth of Si(100) layers by molecular-beam epitaxy. Indium incorporation behavior was studied as a function of ion energy (E+In=50–500 eV), substrate temperature (Ts=500–1050 °C), ion flux (J+In=1×109–5×1012 cm−2 s−1), and Si growth rate (R=0.1–1.3 nm s−1). Dopant concentration profiles obtained using secondary ion mass spectroscopy showed that abrupt doping profiles were obtained at Ts〈900 °C and R=0.7 μm h−1, the incorporation probability σ+In was close to unity for E+In≥200 eV, while σ+In was less than unity and decreased gradually with increasing Ts for E+In≤100 eV. At Ts≥900 °C, σ+In decreased rapidly with increasing Ts for all ion energies. The incorporation results are interpreted using a qualitative model based on different types of binding sites for In with incident energies ranging from thermal to 500 eV. A procedure, utilizing accelerated ions, for the growth of ultrathin doped layers is also suggested.
    Type of Medium: Electronic Resource
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