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  • 1
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Graft polymerization of styrene using a glass fiber having pendent mercaptan groups was carried out under nitrogen in sealed tubes. The percent grafting appeared to increase with monomer concentration, and also to depend to a large extent on the initiator concentration. When CHPO was used as initiator, the percent grafting was maximum at the initiator concentration of 0.02 mol/L. The percent grafting saturation values decreased with increase in the temperature of polymerization. Chain transfer constants and grafting efficiency, both calculated from the equation of Fox et al., were compared with the experimental results. The absorption of Ag ion increased with increase in the percent grafting, and a maximum appeared at a solution pH of 4.0.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 27 (1982), S. 4529-4539 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Modified glass fibers, containing unsaturated hydrocarbon surface groups, were prepared by a hydrothermal treatment, with allylglycidylether in excess as reagent. Graft polymerization of the treated glass fiber with styrene and methylmethacrylate was carried out in sealed tubes, under nitrogen, using benzoyl peroxide (BPO) and cumene hydroperoxide (CHPO) as initiators. When BPO was used as the initiator, the grafting efficiency was extremely low, but the graft copolymerization behavior was similar to that of usual organic polymers. With CHPO, both grafting ratio and grafting efficiency were very high. Various properties of composite materials containing grafted glass cloth were studied. Flexural strength, flexural modulus, and interlaminar shear strength increased proportionally to the increase of the grafting ratio; the same values were decreased only in a small extent after the boiling test.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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