ISSN:
1572-8854
Source:
Springer Online Journal Archives 1860-2000
Topics:
Geosciences
,
Physics
Notes:
Abstract (Chloranilato)bis(tri-n-butylphosphine)palladium(II), [Pd(C6Cl2O4){P(C4H9)3}2] (chloranilic acid=2,5-dichloro-3,6-dihydroxy-p-benzoquinone): FW=718.02,P21/c,a=21.729(6),b=17.293(5),c=21.010(9) Å,β=112.62(3)°,V=7287.42 Å3,Z=8,D c=1.309mg m−3, Mo, λ=0.710730 Å,μ=0.76 mm−1,F(000)=3008, finalR=0.087, 2594 observed reflections. Palladium is ligated by a distorted square planar P2O2 coordination sphere in the title compound. The two molecules per asymmetric unit differ in the arrangement of phosphine n-butyl chains, yielding two unique metal centers.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01160997
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