ISSN:
0009-2940
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
New Reagents, XXXI. Synthesis of (Iodomethyl)-and (Diiodomethyl)element Compounds of the Elements Si, Ge, Sn, PbVia Li—CH2—Hal or Li—CHHal2 (Hal = I, Br), respectively, the monohalides Ph3El—CH2—I (El = Si, Ge, Pb) and Ph3 Ge—CH2—Br have been obtained (49-74%) as well as the dihalides Ph3El—CHI2 (El = Si, Ge, Sn; 49-69%), Ph3Pb—CHI2 (9%), and Ph3Ge—CHBr2 (78%). These compounds are favourable starting materials for corresponding monolithium compounds. Some of them have found synthetic applications.
Additional Material:
3 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19851180137
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